Recent advance in the C–F bond functionalization of trifluoromethyl-containing compounds

G Yan, K Qiu, M Guo - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
The C–F bond is the strongest single bond in organic compounds. It is the most challenging
task to study the activation of the C–F bond in organic synthesis. Trifluoromethyl-containing …

Functionalization of fluorinated molecules by transition-metal-mediated C–F bond activation to access fluorinated building blocks

T Ahrens, J Kohlmann, M Ahrens, T Braun - Chemical Reviews, 2015 - ACS Publications
Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …

Computational studies of synthetically relevant homogeneous organometallic catalysis involving Ni, Pd, Ir, and Rh: an overview of commonly employed DFT methods …

T Sperger, IA Sanhueza, I Kalvet… - Chemical …, 2015 - ACS Publications
The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

Synthesis of fluorinated compounds by nickel-catalyzed defluorinative cross-coupling reactions

K Wang, W Kong - ACS Catalysis, 2023 - ACS Publications
Organofluorine compounds have attracted extensive attention in various industrial fields due
to their unique chemical and physical properties. Despite increasing demand in a wide …

Synthesis of fluorinated building blocks by transition‐metal‐mediated hydrodefluorination reactions

MF Kuehnel, D Lentz, T Braun - … Chemie International Edition, 2013 - Wiley Online Library
The activation and functionalization of carbon–fluorine bonds can be considered as a major
challenge in organometallic chemistry. The growing demand for means to introduce fluorine …

Lewis acidity of organofluorophosphonium salts: hydrodefluorination by a saturated acceptor

CB Caputo, LJ Hounjet, R Dobrovetsky, DW Stephan - Science, 2013 - science.org
Prototypical Lewis acids, such as boranes, derive their reactivity from electronic
unsaturation. Here, we report the Lewis acidity and catalytic application of electronically …

Fluorine and gold: A fruitful partnership

J Miro, C Del Pozo - Chemical reviews, 2016 - ACS Publications
Gold-catalyzed reactions have witnessed an exponential growth in the past decade. When
the unique modes of activation exhibited by gold species meet species with either …

Functional Copolymer Derived Self‐Adapting LiF‐Rich Interphase Toward Deep Cycling Lithium Metal Batteries

A Wang, Y Nie, Y Zhao, D Xu, L Zhang… - Advanced Functional …, 2024 - Wiley Online Library
Lithium metal batteries (LMBs) are the best candidates for high‐energy density system.
However, the unstable solid electrolyte interphase (SEI) caused by notorious lithium …

Activation of C–F bonds α to C–C multiple bonds

JD Hamel, JF Paquin - Chemical Communications, 2018 - pubs.rsc.org
C–F bond activation has drawn a lot of attention in the past, and the case of C (sp3)–F bonds
is particularly interesting as those are the strongest single bonds carbon makes with any …

Carbon–fluorine bond cleavage mediated by metalloenzymes

Y Wang, A Liu - Chemical Society Reviews, 2020 - pubs.rsc.org
Fluorochemicals are a widely distributed class of compounds and have been utilized across
a wide range of industries for decades. Given the environmental toxicity and adverse health …