This review describes the development of enantioselective methods for the ring opening of
cyclopropanes. Both approaches based on the reaction of nonchiral cyclopropanes and …

In this review, transition metal-catalyzed methodologies and applications that exploit C–C
bond cleavage of vinylcyclopropanes (VCPs) are summarized with a focus on cycloaddition …

Ring-opening transformations of donor–acceptor cyclopropanes (DAC) with carbon-
centered nucleophiles is a simple, straight-forward approach to 1, 3-bifunctional compounds …

Visible-light-induced cycloaddition reactions initiated via energy-transfer processes have
recently evolved as powerful methods for the construction of strained cyclic molecules that …

Radical remote 1, n-difunctionalization reactions (n> 2) of alkenes are powerful tools to
efficiently introduce functional groups with selected distances into target molecules. Among …

This review summarizes synthetic developments reported from 1987 to 2019 that exploit C–
C single bond cleavage of cyclopropylamine-based systems. The synthetic and mechanistic …

Conspectus Metal-catalyzed cross-couplings have emerged as essential tools for the
construction of C–C bonds. The identification of efficient catalytic systems as well as large …

Abstract A palladium‐catalyzed asymmetric [4+ 2] cycloaddition of 2‐
methylidenetrimethylene carbonate with alkenes derived from pyrazolones, indandione, or …

The nine-membered ring-bearing bicyclo [5.2. 2] tetrahydrooxonines frameworks have
enantioselectively been constructed via a tandem [3+ 2] cycloaddition/Cope rearrangement …

Transition-metal-catalyzed carbene transfer reactions, involving diazo compounds and their
precursors, are powerful tools for creating new C–C bonds. Depending on the involved …