New advances in the use of infrared absorption spectroscopy for the characterization of heterogeneous catalytic reactions

F Zaera - Chemical Society Reviews, 2014 - pubs.rsc.org
Infrared absorption spectroscopy has proven to be one of the most powerful spectroscopic
techniques available for the characterization of catalytic systems. Although the history of IR …

C− H bond activation and organometallic intermediates on isolated metal centers on oxide surfaces

C Coperet - Chemical reviews, 2010 - ACS Publications
The selective activation and transformation of alkanes or aromatics have been a research
goal for several decades. 1-3 Today, research in this area is strongly motivated by the need …

Electronic modulation of metal-support interactions improves polypropylene hydrogenolysis over ruthenium catalysts

PA Kots, T **e, BC Vance, CM Quinn… - Nature …, 2022 - nature.com
Ruthenium (Ru) is the one of the most promising catalysts for polyolefin hydrogenolysis. Its
performance varies widely with the support, but the reasons remain unknown. Here, we …

The surface chemistry of metal-based hydrogenation catalysis

F Zaera - ACS Catalysis, 2017 - ACS Publications
The promotion of hydrogenation reactions by transition-metal-based heterogeneous
catalysts was established many decades ago but is still quite common in the chemical …

Reaction mechanism and selectivity tuning of propene oxidation at the electrochemical interface

XC Liu, T Wang, ZM Zhang, CH Yang… - Journal of the …, 2022 - ACS Publications
Electrochemical conversion of propene is a promising technique for manufacturing
commodity chemicals by using renewable electricity. To achieve this goal, we still need to …

The reasons why metals catalyze the nucleation and growth of carbon nanotubes and other carbon nanomorphologies

S Esconjauregui, CM Whelan, K Maex - Carbon, 2009 - Elsevier
Carbon nanotubes (CNTs) and other carbon nanomorphologies are grown using
“typical”(Ni, Co, and Fe) and “atypical”(Al, In, Pt, Ti, Mg, Pd, K, Cs, Na, W, Mn, Mo, Ir, and …

Mimicking aspects of heterogeneous catalysis: generating, isolating, and reacting proposed surface intermediates on single crystals in vacuum

BE Bent - Chemical reviews, 1996 - ACS Publications
One of the more controversial issues in surface science concerns the relevance of studies
on singlecrystal surfaces under vacuum conditions for processes such as heterogeneous …

Trends in adsorption characteristics of benzene on transition metal surfaces: Role of surface chemistry and van der Waals interactions

H Yildirim, T Greber, A Kara - The Journal of Physical Chemistry C, 2013 - ACS Publications
The accurate description of interface characteristics between organic molecules and metal
surfaces has long been debated in theoretical studies. A well-founded description of …

Organic chemistry on solid surfaces

Z Ma, F Zaera - Surface science reports, 2006 - Elsevier
Chemistry on solid surfaces is central to many areas of practical interest such as
heterogeneous catalysis, tribology, electrochemistry, and materials processing. With the …

Observing metal-catalyzed chemical reactions in situ using surface-enhanced Raman spectroscopy on Pd− Au nanoshells

KN Heck, BG Janesko, GE Scuseria… - Journal of the …, 2008 - ACS Publications
Insight into the nature of transient reaction intermediates and mechanistic pathways involved
in heterogeneously catalyzed chemical reactions is obtainable from a number of surface …