(4+ 2) Cycloaddition plays an important role in the synthesis of versatile carbocyclic/
heterocyclic compounds with its high atom-and step-economy. Additionally, with mild …

We disclose a transition-metal-free NaI/PPh3-mediated direct C–H alkylation of azauracils
using N-(acyloxy) pthalimides (NHPIs) as readily available alkyl surrogates under visible …

We report a photoredox system comprising sodium iodide, triphenyl phosphine, and N, N,
N′, N′-tetramethylethylenediamine (TMEDA) that can form a self-assembled tetrameric …

A photocatalyst-free and EDA complex-enabled radical cascade cyclization reaction of
inactive alkenes with bromodifluoroacetamides was reported for the divergent synthesis of …

We report an organophotoredox-catalyzed stereoselective allylic arylation of MBH acetates
with a palette of diaryliodonium triflates (DAIRs) to provide the corresponding trisubstituted …

Achieving high molecular complexity can be not trivial, but the exploitation of domino
reactions provides an atom‐and step‐economical method to reach this target. Over the past …

A visible‐light‐promoted strategy for the decarboxylative C‐3 carbamoylation of
quinoxalinone scaffolds is developed. This approach initiates through the formation of an …

We present an electrochemical alkylation of azauracils using N-(acyloxy) phthalimides
(NHPI esters) as readily available alkyl radical progenitors under metal-and additive-free …

We report a metal-and photocatalyst-free C3 α-aminomethylation of quinoxalin-2 (1 H)-ones
with N-alkyl-N-methylanilines. The reaction proceeds through the formation of a …

A photoredox-catalyzed arylative radical cascade involving N-acryloyl-2-
arylbenzoimidazoles and diaryliodonium triflates leading to the formation of a broad array of …