Recent progress in the science of complex coacervation

CE Sing, SL Perry - Soft Matter, 2020 - pubs.rsc.org
Complex coacervation is an associative, liquid–liquid phase separation that can occur in
solutions of oppositely-charged macromolecular species, such as proteins, polymers, and …

Deconstruction and reassembly of renewable polymers and biocolloids into next generation structured materials

BL Tardy, BD Mattos, CG Otoni, M Beaumont… - Chemical …, 2021 - ACS Publications
This review considers the most recent developments in supramolecular and supraparticle
structures obtained from natural, renewable biopolymers as well as their disassembly and …

Driving force and pathway in polyelectrolyte complex coacervation

S Chen, ZG Wang - … of the National Academy of Sciences, 2022 - National Acad Sciences
There is notable discrepancy between experiments and coarse-grained model studies
regarding the thermodynamic driving force in polyelectrolyte complex coacervation …

Design principles for creating synthetic underwater adhesives

A Narayanan, A Dhinojwala, A Joy - Chemical Society Reviews, 2021 - pubs.rsc.org
Water and adhesives have a conflicting relationship as demonstrated by the failure of most
man-made adhesives in underwater environments. However, living creatures routinely …

Driving forces of the complex formation between highly charged disordered proteins

A Chowdhury, A Borgia, S Ghosh… - Proceedings of the …, 2023 - National Acad Sciences
Highly disordered complexes between oppositely charged intrinsically disordered proteins
present a new paradigm of biomolecular interactions. Here, we investigate the driving forces …

Designing electrostatic interactions via polyelectrolyte monomer sequence

TK Lytle, LW Chang, N Markiewicz, SL Perry… - ACS central …, 2019 - ACS Publications
Charged polymers are ubiquitous in biological systems because electrostatic interactions
can drive complicated structure formation and respond to environmental parameters such as …

Understanding the interaction of polyelectrolyte architectures with proteins and biosystems

K Achazi, R Haag, M Ballauff… - Angewandte Chemie …, 2021 - Wiley Online Library
The counterions neutralizing the charges on polyelectrolytes such as DNA or heparin may
dissociate in water and greatly influence the interaction of such polyelectrolytes with …

Lower critical solution temperature-driven self-coacervation of nonionic polyester underwater adhesives

A Narayanan, JR Menefee, Q Liu, A Dhinojwala… - ACS nano, 2020 - ACS Publications
To enable attachment to underwater surfaces, aquatic fauna such as mussels and
sandcastle worms utilize the advantages of coacervation to deliver concentrated protein-rich …

Effects of non-electrostatic intermolecular interactions on the phase behavior of pH-sensitive polyelectrolyte complexes

L Li, S Srivastava, S Meng, JM Ting, MV Tirrell - Macromolecules, 2020 - ACS Publications
Polyelectrolyte complexes (PECs) offer enormous material tunability and desirable
functionalities, and consequently have found broad utility in biomedical and material …

Sequence-dependent self-coacervation in high charge-density polyampholytes

JJ Madinya, LW Chang, SL Perry… - Molecular Systems Design …, 2020 - pubs.rsc.org
Polyampholytes, which contain both positive and negative charges along the backbone,
represent a classical model system for certain types of 'intrinsically-disordered …