Halogen effect in photomechanical molecular crystals

J Zhong, J Sun, K Ye, R Lu - Journal of Materials Chemistry C, 2023 - pubs.rsc.org
Inspired by sophisticated and intelligent biological systems, various smart actuations
triggered by physical or chemical stimuli have been developed. Photomechanical materials …

Optical deformations of azobenzene polymers: orientation approach vs. other concepts

M Saphiannikova, VP Toshchevikov, N Tverdokhleb - Soft Matter, 2024 - pubs.rsc.org
It has been 30 years since the discovery of surface restructuring in thin azopolymer films by
two independent research groups. A wide variety of topographical structures have been …

Photomechanical response of glassy azobenzene polyimide networks

DH Wang, KM Lee, Z Yu, H Koerner, RA Vaia… - …, 2011 - ACS Publications
We report the synthesis of amorphous, heat-resistant (T g ranging from 220 to 246° C)
polyimides cross-linked with a novel tris (azobenzeneamine) cross-linker and examine the …

[KNIHA][B] Azo Polymers

X Wang - 2016 - Springer
This book is about azo polymers including their syntheses, properties, functions, and
applications. Generally speaking, azo polymers are macromolecules that contain a …

Supramolecular azopolymers for dynamic surface microstructures using digital polarization optics

J Strobelt, M Van Soelen, H Abourahma… - Advanced Optical …, 2023 - Wiley Online Library
Thin film supramolecular azopolymers support the all‐optical generation of dynamic surface
microstructures. Using a spatial light modulator (SLM) illuminated at 488 nm, structured …

[HTML][HTML] Mechanics of inhomogeneous large deformation of photo-thermal sensitive hydrogels

W Toh, TY Ng, J Hu, Z Liu - International Journal of Solids and Structures, 2014 - Elsevier
A polymer network can imbibe copious amounts of solvent and swell, the resulting state is
known as a gel. Depending on its constituents, a gel is able to deform under the influence of …

Impact of backbone rigidity on the photomechanical response of glassy, azobenzene-functionalized polyimides

DH Wang, JJ Wie, KM Lee, TJ White, LS Tan - Macromolecules, 2014 - ACS Publications
Azobenzene-functionalized polyimide materials can directly transduce light into mechanical
force. Here, we examine the impact of polymer backbone rigidity on the photomechanical …

Direct observation of athermal photofluidisation in azo-polymer films

N Hurduc, BC Donose, A Macovei, C Paius… - Soft Matter, 2014 - pubs.rsc.org
The surface relief gratings (SRGs) can be generated when azo-polymer films are exposed to
laser beam interference as a result of mass migration. Despite considerable research effort …

Photoisomerization kinetics and mechanical stress in azobenzene-containing materials

V Toshchevikov, J Ilnytskyi… - The journal of physical …, 2017 - ACS Publications
Kinetics of photoisomerization and time evolution of ordering in azobenzene-containing
materials are studied theoretically and by using computer simulations. Starting from kinetic …

Light‐Directed Soft Mass Migration for Micro/Nanophotonics

K Kim, H Park, KJ Park, SH Park… - Advanced Optical …, 2019 - Wiley Online Library
In this review, it is argued that soft mass migrations, driven and guided by spatially controlled
photopolymerization and photochromic isomerization (also called directional plastic …