The transition metal-catalysed hydroboration reaction
The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …
organic molecules was initially realised several decades ago. Although this area of …
s-Block metal catalysts for the hydroboration of unsaturated bonds
The addition of a B–H bond to an unsaturated bond (polarized or unpolarized) is a powerful
and atom-economic tool for the synthesis of organoboranes. In recent years, s-block …
and atom-economic tool for the synthesis of organoboranes. In recent years, s-block …
Ir-Catalyzed Regioselective Dihydroboration of Thioalkynes toward Gem-Diboryl Thioethers
While 1, 1-diboryl (gem-diboryl) compounds are valuable synthetic building blocks,
currently, related studies have mainly focused on those 1, 1-diboryl alkanes without a hetero …
currently, related studies have mainly focused on those 1, 1-diboryl alkanes without a hetero …
One-metal/two-ligand for dual activation tandem catalysis: photoinduced Cu-catalyzed anti-hydroboration of alkynes
A dual catalyst system based on ligand exchange of two diphosphine ligands possessing
different properties in a copper complex has been devised to merge metal-and …
different properties in a copper complex has been devised to merge metal-and …
Homogeneous catalysis with polyhydride complexes
JC Babón, MA Esteruelas, AM López - Chemical Society Reviews, 2022 - pubs.rsc.org
Roles of the hydrogen atoms attached to the metal center of transition metal polyhydride
complexes, LnMHx (x≥ 3), are analyzed for about forty types of organic reactions catalyzed …
complexes, LnMHx (x≥ 3), are analyzed for about forty types of organic reactions catalyzed …
Highly Regioselective Cobalt‐Catalyzed Hydroboration of Internal Alkynes
YD Zhang, XY Li, QK Mo, WB Shi… - Angewandte Chemie …, 2022 - Wiley Online Library
Herein, we report the development of new Co complexes that have cyclopropane‐based
diphosphine ligands and can catalyze highly chemo‐, regio‐, and stereoselective …
diphosphine ligands and can catalyze highly chemo‐, regio‐, and stereoselective …
Iterative Dual-Metal and Energy Transfer Catalysis Enables Stereodivergence in Alkyne Difunctionalization: Carboboration as Case Study
Stereochemically defined tetrasubstituted olefins are widespread structural elements of
organic molecules and key intermediates in organic synthesis. However, flexible methods …
organic molecules and key intermediates in organic synthesis. However, flexible methods …
Metal‐Free Catalytic Hydroboration of Unsaturated Compounds: A Greener Strategy for the Synthesis of Organoboranes
This review discusses the immense progress made over recent years in metal‐free catalytic
hydroboration. Reactions with several unsaturated functional groups, such as alkynes …
hydroboration. Reactions with several unsaturated functional groups, such as alkynes …
Aluminium complexes: next-generation catalysts for selective hydroboration
Organoboranes obtained from hydroboration reactions are one of the important classes of
compounds that could be used to provide valuable synthons for follow-up transformations …
compounds that could be used to provide valuable synthons for follow-up transformations …
Counterion Variation: A Useful Lever for Maximizing the Regioselectivity in the Hydroboration of Terminal Alkynes
A Martínez-Bascuñana, JL Núñez-Rico, L Carreras… - ACS …, 2023 - ACS Publications
The role of the counterion in metal-catalyzed reactions can be crucial as this often-
unconsidered component of the catalyst can modify the performance of the catalyst and …
unconsidered component of the catalyst can modify the performance of the catalyst and …