The transition metal-catalysed hydroboration reaction

SJ Geier, CM Vogels, JA Melanson… - Chemical Society …, 2022 - pubs.rsc.org
The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

s-Block metal catalysts for the hydroboration of unsaturated bonds

M Magre, M Szewczyk, M Rue** - Chemical Reviews, 2022 - ACS Publications
The addition of a B–H bond to an unsaturated bond (polarized or unpolarized) is a powerful
and atom-economic tool for the synthesis of organoboranes. In recent years, s-block …

Ir-Catalyzed Regioselective Dihydroboration of Thioalkynes toward Gem-Diboryl Thioethers

Y Wang, Y Li, L Wang, S Ding, L Song… - Journal of the …, 2023 - ACS Publications
While 1, 1-diboryl (gem-diboryl) compounds are valuable synthetic building blocks,
currently, related studies have mainly focused on those 1, 1-diboryl alkanes without a hetero …

One-metal/two-ligand for dual activation tandem catalysis: photoinduced Cu-catalyzed anti-hydroboration of alkynes

J Corpas, M Gomez-Mendoza… - Journal of the …, 2022 - ACS Publications
A dual catalyst system based on ligand exchange of two diphosphine ligands possessing
different properties in a copper complex has been devised to merge metal-and …

Homogeneous catalysis with polyhydride complexes

JC Babón, MA Esteruelas, AM López - Chemical Society Reviews, 2022 - pubs.rsc.org
Roles of the hydrogen atoms attached to the metal center of transition metal polyhydride
complexes, LnMHx (x≥ 3), are analyzed for about forty types of organic reactions catalyzed …

Highly Regioselective Cobalt‐Catalyzed Hydroboration of Internal Alkynes

YD Zhang, XY Li, QK Mo, WB Shi… - Angewandte Chemie …, 2022 - Wiley Online Library
Herein, we report the development of new Co complexes that have cyclopropane‐based
diphosphine ligands and can catalyze highly chemo‐, regio‐, and stereoselective …

Iterative Dual-Metal and Energy Transfer Catalysis Enables Stereodivergence in Alkyne Difunctionalization: Carboboration as Case Study

J Corpas, M Gomez-Mendoza, EM Arpa… - ACS …, 2023 - ACS Publications
Stereochemically defined tetrasubstituted olefins are widespread structural elements of
organic molecules and key intermediates in organic synthesis. However, flexible methods …

Metal‐Free Catalytic Hydroboration of Unsaturated Compounds: A Greener Strategy for the Synthesis of Organoboranes

A Das, TK Panda - ChemCatChem, 2023 - Wiley Online Library
This review discusses the immense progress made over recent years in metal‐free catalytic
hydroboration. Reactions with several unsaturated functional groups, such as alkynes …

Aluminium complexes: next-generation catalysts for selective hydroboration

A Das, S Rej, TK Panda - Dalton Transactions, 2022 - pubs.rsc.org
Organoboranes obtained from hydroboration reactions are one of the important classes of
compounds that could be used to provide valuable synthons for follow-up transformations …

Counterion Variation: A Useful Lever for Maximizing the Regioselectivity in the Hydroboration of Terminal Alkynes

A Martínez-Bascuñana, JL Núñez-Rico, L Carreras… - ACS …, 2023 - ACS Publications
The role of the counterion in metal-catalyzed reactions can be crucial as this often-
unconsidered component of the catalyst can modify the performance of the catalyst and …