Thiol–ene “click” reactions and recent applications in polymer and materials synthesis: a first update
AB Lowe - Polymer Chemistry, 2014 - pubs.rsc.org
This contribution serves as an update to a previous review (Polym. Chem. 2010, 1, 17–36)
and highlights recent applications of thiol–ene 'click'chemistry as an efficient tool for both …
and highlights recent applications of thiol–ene 'click'chemistry as an efficient tool for both …
Thiol-yne 'click'/coupling chemistry and recent applications in polymer and materials synthesis and modification
AB Lowe - Polymer, 2014 - Elsevier
This review highlights recent applications of the thiol-yne reaction in polymer synthesis and
modification and also gives some representative examples of its application in small …
modification and also gives some representative examples of its application in small …
The thiol-Michael addition click reaction: a powerful and widely used tool in materials chemistry
The key attribute of the thiol-Michael addition reaction that makes it a prized tool in materials
science is its modular “click” nature, which allows for the implementation of this highly …
science is its modular “click” nature, which allows for the implementation of this highly …
Click chemistry in materials science
Despite originating only a little more than a decade ago, click chemistry has become one of
the most powerful paradigms in materials science, synthesis, and modification. By …
the most powerful paradigms in materials science, synthesis, and modification. By …
Thiol–maleimide “click” chemistry: evaluating the influence of solvent, initiator, and thiol on the reaction mechanism, kinetics, and selectivity
BH Northrop, SH Frayne, U Choudhary - Polymer Chemistry, 2015 - pubs.rsc.org
The mechanism and kinetics of thiol–maleimide “click” reactions carried out under a variety
of conditions have been investigated computationally and using experimental competition …
of conditions have been investigated computationally and using experimental competition …
State of the art in dual-curing acrylate systems
Acrylate chemistry has found widespread use in dual-curing systems over the years.
Acrylates are cheap, easily handled and versatile monomers that can undergo facile chain …
Acrylates are cheap, easily handled and versatile monomers that can undergo facile chain …
NHC-catalyzed enantioselective access to β-cyano carboxylic esters via in situ substrate alternation and release
Q Wang, S Wu, J Zou, X Liang, C Mou, P Zheng… - Nature …, 2023 - nature.com
A carbene-catalyzed asymmetric access to chiral β-cyano carboxylic esters is disclosed. The
reaction proceeds between β, β-disubstituted enals and aromatic thiols involving …
reaction proceeds between β, β-disubstituted enals and aromatic thiols involving …
Spatial and temporal control of thiol-Michael addition via photocaged superbase in photopatterning and two-stage polymer networks formation
Photochemical processes enable spatial and temporal control of reactions, which can be
implemented as an accurate external control approach in both polymer synthesis and …
implemented as an accurate external control approach in both polymer synthesis and …
Thia‐Michael Addition: An Emerging Strategy in Organic Synthesis
P Wadhwa, A Kharbanda… - Asian Journal of Organic …, 2018 - Wiley Online Library
The thia‐Michael addition reaction has been demonstrated to be a highly powerful tool in
organic synthesis. Indeed, the influential nature of this reaction has been well‐established in …
organic synthesis. Indeed, the influential nature of this reaction has been well‐established in …
Relative reactivity and selectivity of vinyl sulfones and acrylates towards the thiol–Michael addition reaction and polymerization
The reactivity, selectivity and kinetics of vinyl sulfones and acrylates in base and nucleophile-
catalyzed thiol–Michael addition reactions were examined in detail in this study. The vinyl …
catalyzed thiol–Michael addition reactions were examined in detail in this study. The vinyl …