Thiol–ene “click” reactions and recent applications in polymer and materials synthesis: a first update

AB Lowe - Polymer Chemistry, 2014 - pubs.rsc.org
This contribution serves as an update to a previous review (Polym. Chem. 2010, 1, 17–36)
and highlights recent applications of thiol–ene 'click'chemistry as an efficient tool for both …

Thiol-yne 'click'/coupling chemistry and recent applications in polymer and materials synthesis and modification

AB Lowe - Polymer, 2014 - Elsevier
This review highlights recent applications of the thiol-yne reaction in polymer synthesis and
modification and also gives some representative examples of its application in small …

The thiol-Michael addition click reaction: a powerful and widely used tool in materials chemistry

DP Nair, M Podgorski, S Chatani, T Gong… - Chemistry of …, 2014 - ACS Publications
The key attribute of the thiol-Michael addition reaction that makes it a prized tool in materials
science is its modular “click” nature, which allows for the implementation of this highly …

Click chemistry in materials science

W **, TF Scott, CJ Kloxin… - Advanced Functional …, 2014 - Wiley Online Library
Despite originating only a little more than a decade ago, click chemistry has become one of
the most powerful paradigms in materials science, synthesis, and modification. By …

Thiol–maleimide “click” chemistry: evaluating the influence of solvent, initiator, and thiol on the reaction mechanism, kinetics, and selectivity

BH Northrop, SH Frayne, U Choudhary - Polymer Chemistry, 2015 - pubs.rsc.org
The mechanism and kinetics of thiol–maleimide “click” reactions carried out under a variety
of conditions have been investigated computationally and using experimental competition …

State of the art in dual-curing acrylate systems

O Konuray, X Fernández-Francos, X Ramis, À Serra - Polymers, 2018 - mdpi.com
Acrylate chemistry has found widespread use in dual-curing systems over the years.
Acrylates are cheap, easily handled and versatile monomers that can undergo facile chain …

NHC-catalyzed enantioselective access to β-cyano carboxylic esters via in situ substrate alternation and release

Q Wang, S Wu, J Zou, X Liang, C Mou, P Zheng… - Nature …, 2023 - nature.com
A carbene-catalyzed asymmetric access to chiral β-cyano carboxylic esters is disclosed. The
reaction proceeds between β, β-disubstituted enals and aromatic thiols involving …

Thia‐Michael Addition: An Emerging Strategy in Organic Synthesis

P Wadhwa, A Kharbanda… - Asian Journal of Organic …, 2018 - Wiley Online Library
The thia‐Michael addition reaction has been demonstrated to be a highly powerful tool in
organic synthesis. Indeed, the influential nature of this reaction has been well‐established in …

Relative reactivity and selectivity of vinyl sulfones and acrylates towards the thiol–Michael addition reaction and polymerization

S Chatani, DP Nair, CN Bowman - Polymer Chemistry, 2013 - pubs.rsc.org
The reactivity, selectivity and kinetics of vinyl sulfones and acrylates in base and nucleophile-
catalyzed thiol–Michael addition reactions were examined in detail in this study. The vinyl …