Many-Body Effects at Heterogeneous Interfaces from First-Principles: Progress, Challenges, and Opportunities

ZF Liu - ACS nano, 2025 - ACS Publications
Heterogeneous interfaces are pivotal in numerous nanoscale devices and applications. First-
principles approaches based on quantum mechanics and atomistic structures provide …

[HTML][HTML] An optimally tuned range-separated hybrid starting point for ab initio GW plus Bethe–Salpeter equation calculations of molecules

CA McKeon, SM Hamed, F Bruneval… - The Journal of Chemical …, 2022 - pubs.aip.org
The ab initio GW plus Bethe–Salpeter equation (GW-BSE, where G is the one particle
Green's function and W is the screened Coulomb interaction) approach has emerged as a …

Linear scaling calculations of excitation energies with active-space particle–particle random-phase approximation

J Li, J Yu, Z Chen, W Yang - The Journal of Physical Chemistry A, 2023 - ACS Publications
We developed an efficient active-space particle–particle random-phase approximation
(ppRPA) approach to calculate accurate charge-neutral excitation energies of molecular …

Electronic excited states from a variance-based contracted quantum eigensolver

Y Wang, DA Mazziotti - Physical Review A, 2023 - APS
Electronic excited states of molecules are central to many physical and chemical processes,
and yet they are typically more difficult to compute than ground states. In this paper we …

Combining Renormalized Singles GW Methods with the Bethe–Salpeter Equation for Accurate Neutral Excitation Energies

J Li, D Golze, W Yang - Journal of chemical theory and …, 2022 - ACS Publications
We apply the renormalized singles (RS) Green's function in the Bethe–Salpeter equation
(BSE)/GW approach to predict accurate neutral excitation energies of molecular systems …

Renormalized Singles with Correlation in GW Green's Function Theory for Accurate Quasiparticle Energies

J Li, W Yang - The Journal of Physical Chemistry Letters, 2022 - ACS Publications
We apply the renormalized singles with the correlation (RSc) Green function in the GW
approximation for accurate quasiparticle (QP) energies and orbitals. The RSc Green function …

BSE@GW Prediction of Charge Transfer Exciton in Molecular Complexes: Assessment of Self-Energy and Exchange-Correlation Dependence

S Bhattacharya, J Li, W Yang… - The Journal of Physical …, 2024 - ACS Publications
The Bethe–Salpeter equation using the GW approximation to the self-energy (BSE@ GW) is
a computationally attractive method for studying electronic excitation from first principles …

Accurate Prediction of Core Level Binding Energies from Ground-State Density Functional Calculations: The Importance of Localization and Screening

J Yu, Y Mei, Z Chen, W Yang - arxiv preprint arxiv:2406.06345, 2024 - arxiv.org
A new method for predicting core level binding energies (CLBEs) is developed by both
localizing the core-level states and describing the screening effect. CLBEs contain important …

Energy-Specific Bethe-Salpeter Equation Implementation for Efficient Optical Spectrum Calculations

C Hillenbrand, J Li, T Zhu - arxiv preprint arxiv:2410.24168, 2024 - arxiv.org
We present an energy-specific Bethe-Salpeter equation (BSE) implementation for efficient
core and valence optical spectrum calculations. In energy-specific BSE, high-lying excitation …

Localized Orbital Scaling Correction with Linear Response in Materials

JZ Williams, W Yang - arxiv preprint arxiv:2406.07351, 2024 - arxiv.org
Density functional theory (DFT) is a powerful tool for quantum-mechanical calculations, but
practical calculations suffer systematic errors like incorrect charge densities and total …