N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented …
The stabilization and isolation of highly reactive species has long been the subject of
chemical research. This review will focus on a large and important class of reactive species …
chemical research. This review will focus on a large and important class of reactive species …
Stable heavier carbene analogues
In recent decades, it has generally been recognized that carbenes play an important role as
transient intermediates. As a result of a number of stable carbenes having been isolated and …
transient intermediates. As a result of a number of stable carbenes having been isolated and …
Benchmark Study on the Calculation of 207Pb NMR Chemical Shifts
T Gasevic, JB Kleine Büning, S Grimme… - Inorganic …, 2024 - ACS Publications
A benchmark set for the computation of 207Pb nuclear magnetic resonance (NMR) chemical
shifts is presented. The PbS50 set includes conformer ensembles of 50 lead-containing …
shifts is presented. The PbS50 set includes conformer ensembles of 50 lead-containing …
Transition‐Metal Complexes of Tetrylones [(CO)5W‐E(PPh3)2] and Tetrylenes [(CO)5W‐NHE] (E=C–Pb): A Theoretical Study
TAN Nguyen, G Frenking - Chemistry–A European Journal, 2012 - Wiley Online Library
Quantum chemical calculations at the BP86/TZVPP//BP86/SVP level are performed for the
tetrylone complexes [W (CO) 5‐E (PPh3) 2](W‐1 E) and the tetrylene complexes [W (CO) 5 …
tetrylone complexes [W (CO) 5‐E (PPh3) 2](W‐1 E) and the tetrylene complexes [W (CO) 5 …
Coordination Chemistry of N-Heterocyclic Stannylenes: A Combined Synthetic and Mössbauer Spectroscopy Study
SM Mansell, RH Herber, I Nowik, DH Ross… - Inorganic …, 2011 - ACS Publications
The N-heterocyclic stannylenes (NHSns),[(Dipp) N (CH2) n N (Dipp) S n](Dipp= 2, 6-
iPr2C6H3; n= 2, 1; n= 3, 5) and [(t Bu) N (CHMe) 2N (t Bu) S n](10) are competent ligands …
iPr2C6H3; n= 2, 1; n= 3, 5) and [(t Bu) N (CHMe) 2N (t Bu) S n](10) are competent ligands …
Heterocyclic heavy analogues of carbenes: structure and chemical properties. review
KV Arsenyeva, AV Piskunov - Journal of Structural Chemistry, 2023 - Springer
The paper reviews data reported on the synthesis, molecular and electronic structure of
heterocyclic derivatives of low valent silicon, germanium, tin, and lead for the period from …
heterocyclic derivatives of low valent silicon, germanium, tin, and lead for the period from …
Synthesis and structural characterization of two-coordinate low-valent 14-group metal complexes bearing bulky bis (amido) silane ligands
D Yang, J Guo, H Wu, Y Ding, W Zheng - Dalton Transactions, 2012 - pubs.rsc.org
A series of germylene, stannylene and plumbylene complexes [η2 (N, N)-Me2Si (DippN)
2Ge:](3a),[η2 (N, N)-Ph2Si (DippN) 2Ge:](3b),[η2 (N, N)-Me2Si (DippN) 2Sn:](4),[η2 (N, N) …
2Ge:](3a),[η2 (N, N)-Ph2Si (DippN) 2Ge:](3b),[η2 (N, N)-Me2Si (DippN) 2Sn:](4),[η2 (N, N) …
Designing Stability into Thermally Reactive Plumbylenes
Lead analogues of N-heterocyclic carbenes (NHPbs) are the least understood members of
this increasingly important class of compounds. Here we report the design, preparation …
this increasingly important class of compounds. Here we report the design, preparation …
Heavier N-heterocyclic half-sandwich tetrylenes
IA Bischoff, B Morgenstern, A Schäfer - Chemical Communications, 2022 - pubs.rsc.org
ansa-Half-sandwich complexes of the group 14 elements germanium, tin and lead are
reported, which represent a new class of Lewis amphiphilic tetrylenes and bridge the gap …
reported, which represent a new class of Lewis amphiphilic tetrylenes and bridge the gap …
Reactivity of N-Heterocyclic Stannylenes: Oxidative Addition of Chalcogen Elements to a Chiral NH-Sn System
KR Flanagan, JD Parish, G Kociok-Köhn, AL Johnson - Inorganics, 2023 - mdpi.com
The reactivity of the racemic N-heterocyclic stannylene [{MeHCN (tBu)} Sn](1) with the
chalcogenide elements O2, S, Se, and Te has been investigated. In the case of the reaction …
chalcogenide elements O2, S, Se, and Te has been investigated. In the case of the reaction …