Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

A critically important process in catalysis is the formation of an active catalyst from the
combination of a metal precursor and a ligand, as the efficacy of this reaction governs the …

This review describes the recent advancement of transition metal-catalyzed aromatic carbon-
boron bond construction processes. The efficacy of palladium, nickel and copper catalysis …

A highly selective and general photoinduced C–Cl borylation protocol that employs [Ni
(IMes) 2](IMes= 1, 3-dimesitylimidazoline-2-ylidene) for the radical borylation of …

The nickel-catalyzed Suzuki–Miyaura coupling of aryl halides and phenol-derived
substrates with aryl boronic acids using green solvents, such as 2-Me-THF and tert-amyl …

We report herein a simple, additive-and metal-free, photoinduced, dual C–H/C–X borylation
of chloro-, bromo-, and iodoarenes. The reaction produces 1, 2-and 1, 3-diborylarenes on …

Arylboronic acids are gaining increased importance as reagents and target structures in a
variety of useful applications. Recently, the palladium-catalyzed synthesis of arylboronic …

A zinc (II)/NHC system catalyzes the borylation of aryl halides with diboron (4) reagents in
the presence of KOMe at rt. This transformation can be applied to a broad range of …

Grignard reagents (aliphatic, aromatic, heteroaromatic, vinyl, or allylic) react with 1 equiv of
4, 4, 5, 5-tetramethyl-1, 3, 2-dioxaborolane (pinacolborane, PinBH) at ambient temperature …