Viscoelasticity and dynamics of entangled polymers

H Watanabe - Progress in Polymer Science, 1999 - Elsevier
This article gives a review of the entanglement dynamics of flexible polymer chains from
theoretical and experimental points of view. The global motion of the entangled chains …

Tube theory of entangled polymer dynamics

TCB McLeish - Advances in physics, 2002 - Taylor & Francis
The dynamics of entangled flexible polymers is dominated by physics general to many
chemical systems. It is an appealing interdisciplinary field where experimental and …

Modeling of entangled polymer diffusion in melts and nanocomposites: A review

A Karatrantos, RJ Composto, KI Winey, M Kröger… - Polymers, 2019 - mdpi.com
This review concerns modeling studies of the fundamental problem of entangled
(reptational) homopolymer diffusion in melts and nanocomposite materials in comparison to …

Unexpected power-law stress relaxation of entangled ring polymers

M Kapnistos, M Lang, D Vlassopoulos… - Nature materials, 2008 - nature.com
After many years of intense research, most aspects of the motion of entangled polymers
have been understood. Long linear and branched polymers have a characteristic …

Microscopic theory of linear, entangled polymer chains under rapid deformation including chain stretch and convective constraint release

RS Graham, AE Likhtman, TCB McLeish… - Journal of Rheology, 2003 - pubs.aip.org
A refined version of the Doi and Edwards tube model for entangled polymer liquids is
presented. The model is intended to cover linear chains in the full range of deformation rates …

A molecular theory for fast flows of entangled polymers

DW Mead, RG Larson, M Doi - Macromolecules, 1998 - ACS Publications
The Doi− Edwards (DE) theory for the rheological properties of entangled polymer melts and
solutions successfully predicts the response to large step-shear strains but fails to predict …

Stress relaxation, dynamics, and plasticity of transient polymer networks

F Meng, RH Pritchard, EM Terentjev - Macromolecules, 2016 - ACS Publications
We propose a theoretical framework for dealing with a transient polymer network
undergoing small deformations, based on the rate of breaking and reforming of network …

Shear and extensional rheology of polystyrene melts and solutions with the same number of entanglements

S Costanzo, Q Huang, G Ianniruberto… - …, 2016 - ACS Publications
We investigate the nonlinear shear and uniaxial extensional rheology of entangled
polystyrene (PS) melts and solutions having the same number Z of entanglements, hence …

Self-similar conformations and dynamics in entangled melts and solutions of nonconcatenated ring polymers

T Ge, S Panyukov, M Rubinstein - Macromolecules, 2016 - ACS Publications
A scaling model of self-similar conformations and dynamics of nonconcatenated entangled
ring polymers is developed. Topological constraints force these ring polymers into compact …

Dynamics of a ring polymer in a gel

SP Obukhov, M Rubinstein, T Duke - Physical review letters, 1994 - APS
We present a simple scaling theory of the dynamics of a ring polymer in a gel. In the
absence of excluded volume interactions, we predict that the translational diffusion …