[HTML][HTML] Autonomic Self-Healing of Polymers: Mechanisms, Applications, and Challenges

C Wang, R Boulatov - Molecules, 2025 - mdpi.com
Mechanical loads degrade polymers by enabling mechanochemical fragmentation of
macromolecular backbones. In most polymers, this fragmentation is irreversible, and its …

Constructing Strong and Tough Polymer Elastomers via Photoreversible Coumarin Dimer Mechanophores

L Yuan, X Yang, S Chen, Q Yang, R Fu… - … Applied Materials & …, 2024 - ACS Publications
Advanced elastomers with outstanding strength, toughness, and reusability hold significant
potential for diverse applications. Using photochemistry and mechanochemistry to develop …

Labeling a Polydiene Elastomer with a π-Extended Mechanophore with a Facile and Low Temperature Synthetic Route

A Cartier, O Taisne, S Ivanov, J Caillard, M Couty… - …, 2024 - ACS Publications
Mechanophores are a class of molecules that undergo changes in their optical properties,
following a chemical reaction triggered by a force. Integrated in elastomeric materials, their …

Force-Activated Spin-Crossover in Fe2+ and Co2+ Transition Metal Mechanophores

X Huang, I Kevlishvili, SL Craig, HJ Kulik - Inorganic Chemistry, 2024 - ACS Publications
Transition metal mechanophores exhibiting force-activated spin-crossover are attractive
design targets, yet large-scale discovery of them has not been pursued due in large part to …

Mechanochemistry for On-Demand Polymer Network Materials

ZJ Wang, JP Gong - Macromolecules, 2025 - ACS Publications
Contemporary polymer network materials, such as hydrogels and elastomers, require not
only enhanced mechanical properties but also adaptability during or after use. Polymer …

Theory-driven Discovery of Thermally Stable Mechanophore for Self-strengthening Materials

J Jiang, ZJ Wang, R Staub, Y Harabuchi, A Varnek… - 2024 - chemrxiv.org
Mechanophores that readily undergo bond cleavage upon mechanical stimuli normally
contain a highly strained ring or reactive unit with weak bonds, which are usually thermally …

Quantitative Connection between Macroscopic Stress and Bond-Breaking Force Enabled by Time-Stamped Mechanochemical Fluorescence

J Wang, Z Wang, D Sathe, MC Wang, J Zhou, Z Ling… - 2025 - researchsquare.com
Mechanical stress is ubiquitous in materials, and it is well accepted that stress causes
material wear and failure—which, at the molecular level, results from force-induced bond …