[HTML][HTML] Autonomic Self-Healing of Polymers: Mechanisms, Applications, and Challenges
C Wang, R Boulatov - Molecules, 2025 - mdpi.com
Mechanical loads degrade polymers by enabling mechanochemical fragmentation of
macromolecular backbones. In most polymers, this fragmentation is irreversible, and its …
macromolecular backbones. In most polymers, this fragmentation is irreversible, and its …
Constructing Strong and Tough Polymer Elastomers via Photoreversible Coumarin Dimer Mechanophores
L Yuan, X Yang, S Chen, Q Yang, R Fu… - … Applied Materials & …, 2024 - ACS Publications
Advanced elastomers with outstanding strength, toughness, and reusability hold significant
potential for diverse applications. Using photochemistry and mechanochemistry to develop …
potential for diverse applications. Using photochemistry and mechanochemistry to develop …
Labeling a Polydiene Elastomer with a π-Extended Mechanophore with a Facile and Low Temperature Synthetic Route
A Cartier, O Taisne, S Ivanov, J Caillard, M Couty… - …, 2024 - ACS Publications
Mechanophores are a class of molecules that undergo changes in their optical properties,
following a chemical reaction triggered by a force. Integrated in elastomeric materials, their …
following a chemical reaction triggered by a force. Integrated in elastomeric materials, their …
Force-Activated Spin-Crossover in Fe2+ and Co2+ Transition Metal Mechanophores
Transition metal mechanophores exhibiting force-activated spin-crossover are attractive
design targets, yet large-scale discovery of them has not been pursued due in large part to …
design targets, yet large-scale discovery of them has not been pursued due in large part to …
Mechanochemistry for On-Demand Polymer Network Materials
Contemporary polymer network materials, such as hydrogels and elastomers, require not
only enhanced mechanical properties but also adaptability during or after use. Polymer …
only enhanced mechanical properties but also adaptability during or after use. Polymer …
Theory-driven Discovery of Thermally Stable Mechanophore for Self-strengthening Materials
Mechanophores that readily undergo bond cleavage upon mechanical stimuli normally
contain a highly strained ring or reactive unit with weak bonds, which are usually thermally …
contain a highly strained ring or reactive unit with weak bonds, which are usually thermally …
Quantitative Connection between Macroscopic Stress and Bond-Breaking Force Enabled by Time-Stamped Mechanochemical Fluorescence
Mechanical stress is ubiquitous in materials, and it is well accepted that stress causes
material wear and failure—which, at the molecular level, results from force-induced bond …
material wear and failure—which, at the molecular level, results from force-induced bond …