Atomically dispersed Co-N/C catalyst for divergent synthesis of nitrogen-containing compounds from alkenes
W Xue, Z Zhu, S Chen, B You… - Journal of the American …, 2023 - ACS Publications
Alkene functionalization with a single-atom catalyst (SAC) which merges homogeneous and
heterogeneous catalysis is a fascinating route to obtain high-value-added molecules …
heterogeneous catalysis is a fascinating route to obtain high-value-added molecules …
Homogeneous Iron Catalyzed C− H Amination
D Possenti, G Olivo - ChemCatChem, 2024 - Wiley Online Library
Iron‐catalyzed C− H amination is emerging as an attractive and sustainable method to
install amine functionalities into organic compounds. Amination of C (sp3)− H bonds is …
install amine functionalities into organic compounds. Amination of C (sp3)− H bonds is …
Enzymatic nitrogen incorporation using hydroxylamine
Hydroxylamine-derived reagents have enabled versatile nitrene transfer reactions for
introducing nitrogen-containing functionalities in small-molecule catalysis, as well as …
introducing nitrogen-containing functionalities in small-molecule catalysis, as well as …
Reaction Discovery Using Spectroscopic Insights from an Enzymatic C–H Amination Intermediate
Engineered hemoproteins can selectively incorporate nitrogen from nitrene precursors like
hydroxylamine, O-substituted hydroxylamines, and organic azides into organic molecules …
hydroxylamine, O-substituted hydroxylamines, and organic azides into organic molecules …
Difunctionalization Processes Enabled by Hexafluoroisopropanol
In the past 5 years, hexafluoroisopropanol (HFIP) has been used as a unique solvent or
additive to enable challenging transformations through substrate activation and stabilization …
additive to enable challenging transformations through substrate activation and stabilization …
Harnessing bromo/acyloxy transposition (BrAcT) and excited-state copper catalysis for styrene difunctionalization
1, 2-Difunctionalization of styrenes, adding two distinct functional groups across the C═ C
double bond, has emerged as a powerful tool for enhancing molecular complexity. Herein …
double bond, has emerged as a powerful tool for enhancing molecular complexity. Herein …
Synthesis of Unprotected β‐Arylethylamines by Iron (II)‐Catalyzed 1, 2‐Aminoarylation of Alkenes in Hexafluoroisopropanol
Abstract β‐Arylethylamines are prevalent structural motifs in molecules exhibiting biological
activity. Here we report a sequential one‐pot protocol for the 1, 2‐aminoarylation of alkenes …
activity. Here we report a sequential one‐pot protocol for the 1, 2‐aminoarylation of alkenes …
Direct C− C Double Bond Cleavage of Alkenes Enabled by Highly Dispersed Cobalt Catalyst and Hydroxylamine
The utilization of a single‐atom catalyst to break C− C bonds merges the merits of
homogeneous and heterogeneous catalysis and presents an intriguing pathway for …
homogeneous and heterogeneous catalysis and presents an intriguing pathway for …
Ortho-Selective amination of arene carboxylic acids via rearrangement of acyl O-hydroxylamines
Direct amination of arene C–H bonds is an attractive disconnection to form aniline-derived
building blocks. This transformation presents significant practical challenges; classical …
building blocks. This transformation presents significant practical challenges; classical …
Advancing critical chemical processes for a sustainable future: challenges for industry and the Max Planck–Cardiff centre on the fundamentals of heterogeneous …
Catalysis is involved in around 85% of manufacturing industry and contributes an estimated
25% to the global domestic product, with the majority of the processes relying on …
25% to the global domestic product, with the majority of the processes relying on …