This review deals with some key synthetic developments based on the use of iron or cobalt
complexes to promote radical reactivity which have been devised over the last decades. We …

Amino acids (AAs) play an important role in the modern health industry as key synthetic
precursors for pharmaceuticals, biomaterials, biosensors, and drug delivery systems …

The visible light induced, photocatalysts or photoabsorbing EDA complexes mediated
cleavage of pyridinium CN bond were reported in the past years. Here, we report an ionic …

Synthesis of unnatural amino acids has long been a focus of chemistry research. Here, we
present an efficient, general method that furnishes γ-carbonyl α-amino acids via …

Chiral amino acids (AAs), being the main “building” blocks of the living organisms, are also
an important class of organic compounds which broadly applied in synthetic chemistry …

Tailor-made amino acids are indispensable structural components of modern medicinal
chemistry and drug design. Consequently, stereo-controlled preparation of amino acids is …

An expedient synthesis of β-alkyl α-amino acids is reported via application of
decarboxylative photocatalysis. The method utilizes abundant, diverse, and inexpensive …

The transition metal catalyzed coupling reaction has revolutionized the strategies for forging
the carbon‐carbon bonds. In contrast to traditional cross‐coupling methods using pre …

An enantioselective synthesis of unnatural pyrazole‐based α‐chiral amino acid derivatives
from the asymmetric reaction of N‐aryl‐5‐aminopyrazoles with β, γ‐alkynyl‐α‐imino esters …

We describe herein a convenient strategy for the construction of C, C-glycoside building
blocks via the intermediacy of tertiary pseudoanomeric radicals. Application of an iron …