Propeller‐Shaped Fe4 and Fe3M Molecular Nanomagnets: A Journey from Crystals to Addressable Single Molecules

A Cornia, M Mannini, R Sessoli… - European Journal of …, 2019 - Wiley Online Library
This Microreview covers the preparation and investigation of Fe4 and Fe3M complexes with
a propeller‐like structure, most of which function as single‐molecule magnets (SMMs). The …

Understanding the Spin of Metal Complexes from a Single‐Molecule Perspective

J Guo, Q Gao, F Gao, C Jia, X Guo - Small Methods, 2024 - Wiley Online Library
Compared with aggregate spin behavior, single‐molecule spin behavior can be accurately
understood, controlled, and applied at the level of basic building blocks. The potential of …

Measuring giant anisotropy in paramagnetic transition metal complexes with relevance to single-ion magnetism

J Krzystek, J Telser - Dalton Transactions, 2016 - pubs.rsc.org
“Giant magnetic anisotropy” is a phenomenon identified fairly recently in coordination
complexes of nd-and nf-block ions. It can have different origins but is commonly (if not …

Exchange coupling inversion in a high-spin organic triradical molecule

R Gaudenzi, E Burzurí, D Reta, IPR Moreira… - Nano Letters, 2016 - ACS Publications
The magnetic properties of a nanoscale system are inextricably linked to its local
environment. In adatoms on surfaces and inorganic layered structures, the exchange …

Redox-induced gating of the exchange interactions in a single organic diradical

R Gaudenzi, J De Bruijckere, D Reta, IPR Moreira… - ACS …, 2017 - ACS Publications
Embedding a magnetic electroactive molecule in a three-terminal junction allows for the fast
and local electric field control of magnetic properties desirable in spintronic devices and …

Spin-state dependent conductance switching in single molecule-graphene junctions

E Burzurí, A García-Fuente, V García-Suárez… - Nanoscale, 2018 - pubs.rsc.org
Spin-crossover (SCO) molecules are versatile magnetic switches with applications in
molecular electronics and spintronics. Downscaling devices to the single-molecule level …

Multiscale study of mononuclear Co II SMMs based on curcuminoid ligands

R Díaz-Torres, M Menelaou, O Roubeau, A Sorrenti… - Chemical …, 2016 - pubs.rsc.org
This work introduces a novel family of CoII species having a curcuminoid (CCMoid) ligand,
9Accm, attached, namely [Co (9Accm) 2 (py) 2](1) and [Co (9Accm) 2 (2, 2′-bpy)](2) …

Ground-state spin blockade in a single-molecule junction

J de Bruijckere, P Gehring, M Palacios-Corella… - Physical Review Letters, 2019 - APS
It is known that the quantum mechanical ground state of a nanoscale junction has a
significant impact on its electrical transport properties. This becomes particularly important in …

Engineering Chemisorption of Fe4 Single‐Molecule Magnets on Gold

L Poggini, E Tancini, C Danieli… - Advanced Materials …, 2021 - Wiley Online Library
Gaining control over the grafting geometry is critically important for any application of surface‐
supported single‐molecule magnets (SMMs) in data storage, spintronics, and quantum …

Highly Ordered Surface Self-Assembly of Fe4 Single Molecule Magnets

P Erler, P Schmitt, N Barth, A Irmler, S Bouvron… - Nano …, 2015 - ACS Publications
Single molecule magnets (SMMs) have attracted considerable attention due to low-
temperature magnetic hysteresis and fascinating quantum effects. The investigation of these …