1, 1, 1, 3, 3, 3-Hexafluoroisopropanol (HFIP) is a polar, strongly hydrogen bond-donating
solvent that has found numerous uses in organic synthesis due to its ability to stabilize ionic …

This review introduces the synthetic organic chemical value of α‐bromocarbonyl compounds
with tertiary carbons. This α‐bromocarbonyl compound with a tertiary carbon has been used …

An atom economical and environmentally benign protocol has been developed for the
regioselective C (sp2)–H bond functionalization of indolizines. The acetic acid-catalyzed …

Herein, we report a highly efficient and unprecedented approach for heteroarylation of
congested α-bromoamides via electrophilic aromatic substitution of imidazo-heteroarenes …

Herein, we report a new and highly efficient approach for synthesizing congested α-
thioamides under mild reaction conditions (mild base, room temperature, and short duration) …

Aza‐oxyallyl cations, as proposed by Sheehan in the 1960s have garnered significant
attention among the synthetic organic community, owing to their diverse reactivity profile for …

Pure quantum mechanical calculations were performed to find out the origin of
regioselectivity under the metalloradical catalysis (MRC) by Co (II)-porphyrin, which showed …

The cycloaddition reactions between isatin azomethine imine and in situ generated
azaoxyallyl cation were explored by density functional theory calculations to elucidate the …

This chapter reviews pericyclic reactions in general and reactions where a cascade of
concerted processes with transition states representing superpositions of two pericyclic …