Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical Communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

2p–3d–4f hetero-tri-spin molecule-based magnetic compounds

M Zhu, L Li, JP Sutter - Inorganic Chemistry Frontiers, 2016 - pubs.rsc.org
The promising magnetic behavior of heterospin systems has spurred the research of 2p–3d–
4f hetero-tri-spin compounds. Such a magnetic system has crucial advantages: the strongest …

Ab initio investigation of the non-collinear magnetic structure and the lowest magnetic excitations in dysprosium triangles

L Ungur, W Van den Heuvel, LF Chibotaru - New Journal of Chemistry, 2009 - pubs.rsc.org
The unusual magnetism exhibited by dysprosium triangles [Dy3 (μ3-OH) 2L3Cl2 (H2O)
4][Dy3 (μ3-OH) 2L3Cl (H2O) 5] Cl5· 19H2O is explained using the recently developed ab …

Fine-Tuning Ligand to Modulate the Magnetic Anisotropy in a Carboxylate-Bridged Dy2 Single-Molecule Magnet System

YL Wang, CB Han, YQ Zhang, QY Liu, CM Liu… - Inorganic …, 2016 - ACS Publications
A series of dinuclear Dy (III) compounds with the general formula [Dy2 (μ2-anthc) 4 (anthc) 2
(L) 2](anthc–= 9-anthracenecarboxylate, L= 2, 2′-bipyridyl (1), 1, 10-phenanthroline (2) …

Slow magnetic relaxation in lanthanide complexes with chelating nitronyl nitroxide radical

XL Wang, LC Li, DZ Liao - Inorganic chemistry, 2010 - ACS Publications
Two rare-earth radical complexes [Ln (hfac) 3NIT-2Py]· 0.5 C7H16 [Ln= Tb (1), Dy (2)] have
been synthesized and characterized structurally as well as magnetically. Both complexes …

Rational enhancement of the energy barrier of bis (tetrapyrrole) dysprosium SMMs via replacing atom of porphyrin core

W Cao, C Gao, YQ Zhang, D Qi, T Liu, K Wang… - Chemical …, 2015 - pubs.rsc.org
With the coordination geometry of DyIII being relatively fixed, oxygen and sulfur atoms were
used to replace one porphyrin pyrrole nitrogen atom of sandwich complex [(Bu) 4N][DyIII …

Reinforced room-temperature spin filtering in chiral paramagnetic metallopeptides

R Torres-Cavanillas, G Escorcia-Ariza… - Journal of the …, 2020 - ACS Publications
Chirality-induced spin selectivity (CISS), whereby helical molecules polarize the spin of
electrical current, is an intriguing effect with potential applications in nanospintronics. In this …

Exchange‐Biasing in a Dinuclear Dysprosium (III) Single‐Molecule Magnet with a Large Energy Barrier for Magnetisation Reversal

T Han, MJ Giansiracusa, ZH Li, YS Ding… - … A European Journal, 2020 - Wiley Online Library
A dichlorido‐bridged dinuclear dysprosium (III) single‐molecule magnet [Dy2L2 (μ‐Cl) 2
(thf) 2] has been made by using a diamine‐bis (phenolate) ligand, H2L. Magnetic studies …

Smooth transition between SMM and SCM-type slow relaxing dynamics for a 1-D assemblage of {Dy (nitronyl nitroxide) 2} units

R Liu, L Li, X Wang, P Yang, C Wang, D Liao… - Chemical …, 2010 - pubs.rsc.org
A model example for size effects on the dynamic susceptibility behavior is provided by the
chain compound [{Dy (hfac) 3NitPhIm2} Dy (hfac) 3](NitPhIm= 2-[4-(1-imidazole) phenyl] …