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Radical ligand-containing single-molecule magnets
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …
and processing; however, such applications require large spin relaxation barriers and …
Single-molecule magnet engineering: building-block approaches
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …
the constituent metal ion building blocks. Although this general approach does not seem to …
2p–3d–4f hetero-tri-spin molecule-based magnetic compounds
M Zhu, L Li, JP Sutter - Inorganic Chemistry Frontiers, 2016 - pubs.rsc.org
The promising magnetic behavior of heterospin systems has spurred the research of 2p–3d–
4f hetero-tri-spin compounds. Such a magnetic system has crucial advantages: the strongest …
4f hetero-tri-spin compounds. Such a magnetic system has crucial advantages: the strongest …
Ab initio investigation of the non-collinear magnetic structure and the lowest magnetic excitations in dysprosium triangles
The unusual magnetism exhibited by dysprosium triangles [Dy3 (μ3-OH) 2L3Cl2 (H2O)
4][Dy3 (μ3-OH) 2L3Cl (H2O) 5] Cl5· 19H2O is explained using the recently developed ab …
4][Dy3 (μ3-OH) 2L3Cl (H2O) 5] Cl5· 19H2O is explained using the recently developed ab …
Fine-Tuning Ligand to Modulate the Magnetic Anisotropy in a Carboxylate-Bridged Dy2 Single-Molecule Magnet System
YL Wang, CB Han, YQ Zhang, QY Liu, CM Liu… - Inorganic …, 2016 - ACS Publications
A series of dinuclear Dy (III) compounds with the general formula [Dy2 (μ2-anthc) 4 (anthc) 2
(L) 2](anthc–= 9-anthracenecarboxylate, L= 2, 2′-bipyridyl (1), 1, 10-phenanthroline (2) …
(L) 2](anthc–= 9-anthracenecarboxylate, L= 2, 2′-bipyridyl (1), 1, 10-phenanthroline (2) …
Slow magnetic relaxation in lanthanide complexes with chelating nitronyl nitroxide radical
XL Wang, LC Li, DZ Liao - Inorganic chemistry, 2010 - ACS Publications
Two rare-earth radical complexes [Ln (hfac) 3NIT-2Py]· 0.5 C7H16 [Ln= Tb (1), Dy (2)] have
been synthesized and characterized structurally as well as magnetically. Both complexes …
been synthesized and characterized structurally as well as magnetically. Both complexes …
Rational enhancement of the energy barrier of bis (tetrapyrrole) dysprosium SMMs via replacing atom of porphyrin core
W Cao, C Gao, YQ Zhang, D Qi, T Liu, K Wang… - Chemical …, 2015 - pubs.rsc.org
With the coordination geometry of DyIII being relatively fixed, oxygen and sulfur atoms were
used to replace one porphyrin pyrrole nitrogen atom of sandwich complex [(Bu) 4N][DyIII …
used to replace one porphyrin pyrrole nitrogen atom of sandwich complex [(Bu) 4N][DyIII …
Reinforced room-temperature spin filtering in chiral paramagnetic metallopeptides
Chirality-induced spin selectivity (CISS), whereby helical molecules polarize the spin of
electrical current, is an intriguing effect with potential applications in nanospintronics. In this …
electrical current, is an intriguing effect with potential applications in nanospintronics. In this …
Exchange‐Biasing in a Dinuclear Dysprosium (III) Single‐Molecule Magnet with a Large Energy Barrier for Magnetisation Reversal
A dichlorido‐bridged dinuclear dysprosium (III) single‐molecule magnet [Dy2L2 (μ‐Cl) 2
(thf) 2] has been made by using a diamine‐bis (phenolate) ligand, H2L. Magnetic studies …
(thf) 2] has been made by using a diamine‐bis (phenolate) ligand, H2L. Magnetic studies …
Smooth transition between SMM and SCM-type slow relaxing dynamics for a 1-D assemblage of {Dy (nitronyl nitroxide) 2} units
R Liu, L Li, X Wang, P Yang, C Wang, D Liao… - Chemical …, 2010 - pubs.rsc.org
A model example for size effects on the dynamic susceptibility behavior is provided by the
chain compound [{Dy (hfac) 3NitPhIm2} Dy (hfac) 3](NitPhIm= 2-[4-(1-imidazole) phenyl] …
chain compound [{Dy (hfac) 3NitPhIm2} Dy (hfac) 3](NitPhIm= 2-[4-(1-imidazole) phenyl] …