Transition metal-catalyzed C–H amination: scope, mechanism, and applications
Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …
synthetic approach to construct N-functionalized molecules. Over the last few decades …
Transition-metal-catalyzed C–N bond forming reactions using organic azides as the nitrogen source: a journey for the mild and versatile C–H amination
Conspectus Owing to the prevalence of nitrogen-containing compounds in functional
materials, natural products and important pharmaceutical agents, chemists have actively …
materials, natural products and important pharmaceutical agents, chemists have actively …
Catalytic methods for aromatic C–H amination: an ideal strategy for nitrogen-based functional molecules
Transformations of aromatic compounds into the corresponding amines, amides, and imides
through carbon–hydrogen (C–H) bond functionalization represent one of the most step-and …
through carbon–hydrogen (C–H) bond functionalization represent one of the most step-and …
Mechanistic studies on the Rh (III)-mediated amido transfer process leading to robust C–H amination with a new type of amidating reagent
Mechanistic investigations on the Cp* Rh (III)-catalyzed direct C–H amination reaction led us
to reveal the new utility of 1, 4, 2-dioxazol-5-one and its derivatives as highly efficient amino …
to reveal the new utility of 1, 4, 2-dioxazol-5-one and its derivatives as highly efficient amino …
Comparative Catalytic Activity of Group 9 [Cp*MIII] Complexes: Cobalt‐Catalyzed CH Amidation of Arenes with Dioxazolones as Amidating Reagents
J Park, S Chang - Angewandte Chemie International Edition, 2015 - Wiley Online Library
A procedure for the [Cp* CoIII]‐catalyzed direct C H amidation of arenes with dioxazolone
has been developed. This reaction proceeds under straightforward and mild conditions with …
has been developed. This reaction proceeds under straightforward and mild conditions with …
Synthesis of complex bicyclic scaffolds by intermolecular photosensitized dearomative cycloadditions of activated alkenes and naphthalenes
The rapid buildup of molecular complexity from simple precursors is a key goal in organic
chemistry. One strategy to achieve this is through a dearomative cycloaddition wherein a 2D …
chemistry. One strategy to achieve this is through a dearomative cycloaddition wherein a 2D …
Cooperative Effects between Chiral Cpx–Iridium(III) Catalysts and Chiral Carboxylic Acids in Enantioselective C−H Amidations of Phosphine Oxides
YS Jang, M Dieckmann, N Cramer - Angewandte Chemie, 2017 - Wiley Online Library
An enantioselective C− H amidation of phosphine oxides by using an iridium (III) catalyst
bearing an atropchiral cyclopentadienyl (Cpx) ligand is reported. A very strong cooperative …
bearing an atropchiral cyclopentadienyl (Cpx) ligand is reported. A very strong cooperative …
Mechanochemical Iridium (III)‐Catalyzed C− H Bond Amidation of Benzamides with Sulfonyl Azides under Solvent‐Free Conditions in a Ball Mill
Mechanochemical conditions have been applied to an iridium (III)‐catalyzed C− H bond
amidation process for the first time. In the absence of solvent, the mechanochemical …
amidation process for the first time. In the absence of solvent, the mechanochemical …
Direct Synthesis of N-H Carbazoles via Iridium(III)-Catalyzed Intramolecular C–H Amination
C Suzuki, K Hirano, T Satoh, M Miura - Organic letters, 2015 - ACS Publications
The iridium-catalyzed dehydrogenative cyclization of 2-aminobiphenyls proceeds smoothly
in the presence of a copper cocatalyst under air as a terminal oxidant through intramolecular …
in the presence of a copper cocatalyst under air as a terminal oxidant through intramolecular …
Recent developments in P (O/S)–N containing flame retardants
Synthesis of organophosphorus compounds containing nitrogen as heteroatom and its
application as a flame retardant (FR) have attracted much attention in the academic and …
application as a flame retardant (FR) have attracted much attention in the academic and …