The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

The introduction of the E Factor in 1992 focussed attention on the problem of waste
generation, defined as everything but the desired product, in chemicals manufacture and …

Entropy plays a pivotal role in catalysis, and extensive research efforts have been directed to
understanding the enthalpy-entropy relationship that defines the reaction pathways of …

Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …

Heterogeneous single-cluster catalysts (SCCs) comprising atomically precise and isolated
metal clusters stabilized on appropriately chosen supports offer exciting prospects for …

Proton-coupled electron transfer (PCET) plays an essential role in a wide range of
electrocatalytic processes. A vast array of theoretical and computational methods have been …

Multi-metal oxides in general and perovskite oxides in particular have attracted considerable
attention as oxygen evolution electrocatalysts. Although numerous theoretical studies have …

Ammonia is a crucial chemical in agriculture, industry, and emerging energy industries, so
high‐efficient, energy‐saving, sustainable, and environmentally‐friendly NH3 synthesis …

Understanding the chemistry underpinning intermetallic synergy and the discovery of
generally applicable structure-performances relationships are major challenges in catalysis …

Disproportionation and comproportionation reactions have become increasingly important
electron transfer events in organometallic chemistry and catalysis. The renewed interest in …