The introduction of the E Factor in 1992 focussed attention on the problem of waste
generation, defined as everything but the desired product, in chemicals manufacture and …

Heterogeneous single-cluster catalysts (SCCs) comprising atomically precise and isolated
metal clusters stabilized on appropriately chosen supports offer exciting prospects for …

The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …

For practical photoelectrochemical water splitting to become a reality, highly efficient, stable
and scalable photoelectrodes are essential. However, meeting these requirements …

Entropy plays a pivotal role in catalysis, and extensive research efforts have been directed to
understanding the enthalpy-entropy relationship that defines the reaction pathways of …

Proton-coupled electron transfer (PCET) plays an essential role in a wide range of
electrocatalytic processes. A vast array of theoretical and computational methods have been …

Precious metals are core assets for the development of modern technologies in various
fields. Their scarcity poses the question of their cost, life cycle and reuse. Recently, an …

Multi-metal oxides in general and perovskite oxides in particular have attracted considerable
attention as oxygen evolution electrocatalysts. Although numerous theoretical studies have …

Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …