Direct photocatalyzed hydrogen atom transfer (HAT) for aliphatic C–H bonds elaboration
Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …
Strategies to generate nitrogen-centered radicals that may rely on photoredox catalysis: development in reaction methodology and applications in organic synthesis
For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …
synthetic intermediates. This review is a survey designed for use by chemists engaged in …
[HTML][HTML] Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium,(ii) iridium and (iii) organic photoredox agents
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …
years, but such is the pace of progress that we will overlap very little with earlier …
Visible light photocatalysis in the late-stage functionalization of pharmaceutically relevant compounds
The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …
to speed up the identification of structure–activity relationships (SARs) and to optimize …
Light in gold catalysis
Within the wide family of gold-catalyzed reactions, gold photocatalysis intrinsically features
unique elementary steps. When gold catalysis meets photocatalysis, a valence change of …
unique elementary steps. When gold catalysis meets photocatalysis, a valence change of …
Generation of alkyl radicals: from the tyranny of tin to the photon democracy
Alkyl radicals are key intermediates in organic synthesis. Their classic generation from alkyl
halides has a severe drawback due to the employment of toxic tin hydrides to the point that …
halides has a severe drawback due to the employment of toxic tin hydrides to the point that …
3d transition metals for C–H activation
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …
notable applications to material sciences, crop protection, drug discovery, and …
Radical generation and fate control for photocatalytic biomass conversion
Photocatalysis is an emerging approach for sustainable chemical production from
renewable biomass under mild conditions. Active radicals are always generated as key …
renewable biomass under mild conditions. Active radicals are always generated as key …
Aroyl fluorides as bifunctional reagents for dearomatizing fluoroaroylation of benzofurans
The 2, 3-dihydrobenzofuran scaffold is widely found in natural products and biologically
active compounds. Herein, dearomatizing 2, 3-fluoroaroylation of benzofurans with aroyl …
active compounds. Herein, dearomatizing 2, 3-fluoroaroylation of benzofurans with aroyl …
Thermocatalytic Conversion of CO2 to Valuable Products Activated by Noble‐Metal‐Free Metal‐Organic Frameworks
SL Hou, J Dong, XY Zhao, XS Li, FY Ren… - Angewandte Chemie …, 2023 - Wiley Online Library
Thermocatalysis of CO2 into high valuable products is an efficient and green method for
mitigating global warming and other environmental problems, of which Noble‐metal‐free …
mitigating global warming and other environmental problems, of which Noble‐metal‐free …