Organoboron compounds as versatile reagents in the transition metal-catalyzed C–S, C–Se and C–Te bond formation

AM Barcellos, M Sacramento, GP da Costa… - Coordination Chemistry …, 2021 - Elsevier
Organochalcogen compounds present synthetic and biological applications of extreme
relevance. The coupling reaction between boronic acids, borate anions or boronic esters …

Organosulphur and organoselenium compounds as ligands for catalytic systems in the Sonogashira coupling

S Purohit, R Rana, A Tyagi, A Bahuguna… - Organic & …, 2024 - pubs.rsc.org
Sonogashira coupling is a reaction of aryl/vinyl halides with terminal alkynes that leads to
the synthesis of conjugated enynes. Generally, the presence of copper (Cu) is required as a …

Tetravalent Spiroselenurane Catalysts: Intramolecular Se···N Chalcogen Bond-Driven Catalytic Disproportionation of H2O2 to H2O and O2 and Activation of I2 and …

M Batabyal, A Upadhyay, R Kadu… - Inorganic …, 2022 - ACS Publications
Chalcogen-bonding interactions have recently gained considerable attention in the field of
synthetic chemistry, structure, and bonding. Here, three organo-spiroselenuranes, having a …

Selenols: A new class of carbonic anhydrase inhibitors

A Angeli, D Tanini, A Nocentini, A Capperucci… - Chemical …, 2019 - pubs.rsc.org
Stable aryl selenols were obtained through a convenient procedure. Selenols represent a
new chemotype acting as carbonic anhydrase inhibitors (CAIs), inhibiting four human …

Synthesis of functionalised organochalcogenides and in vitro evaluation of their antioxidant activity

A Capperucci, M Coronnello, F Salvini, D Tanini… - Bioorganic …, 2021 - Elsevier
Differently substituted β-hydroxy-and β-amino dialkyl and alkyl-aryl tellurides and selenides
have been prepared through ring-opening reactions of epoxides and aziridines with …

Direct biocatalysed synthesis of first sulfur-, selenium-and tellurium-containing l-ascorbyl hybrid derivatives with radical trap** and GPx-like properties

D Tanini, B Lupori, G Malevolti, M Ambrosi… - Chemical …, 2019 - pubs.rsc.org
6-OL-Ascorbyl selenoesters, thioesters and telluroesters can be efficiently and directly
prepared from L-ascorbic acid and suitable functionalised chalcogenoesters through lipase …

Ring opening reactions of heterocycles with selenium and tellurium nucleophiles

D Tanini, A Capperucci - New Journal of Chemistry, 2019 - pubs.rsc.org
An overview of the preparation and synthetic potentialities of functionalized organoselenium
and organotellurium compounds is presented. Various methods to generate selenated or …

The polyhedral nature of selenium-catalysed reactions: Se (iv) species instead of Se (vi) species make the difference in the on water selenium-mediated oxidation of …

D Tanini, C Dalia, A Capperucci - Green Chemistry, 2021 - pubs.rsc.org
Selenium-catalysed oxidations are highly sought after in organic synthesis and biology.
Herein, we report our studies on the on water selenium mediated oxidation of anilines. In the …

Sulfur, selenium and tellurium containing amines act as effective carbonic anhydrase activators

D Tanini, A Capperucci, CT Supuran, A Angeli - Bioorganic Chemistry, 2019 - Elsevier
A new series of β-aminochalcogenides were designed and synthesized to identify new
carbonic anhydrase activator (CAA) agents as novel tools for the management of several …

Carbonic Anhydrase inhibitors bearing organotelluride moieties as novel agents for antitumor therapy

A Petreni, A Iacobescu, N Simionescu… - European Journal of …, 2022 - Elsevier
Solid tumors are mainly characterized by a specific hypoxic microenvironment which makes
them particularly challenging to treat. The Carbonic Anhydrase IX (CA IX) is one of the major …