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Recent advances in catalytic and non-catalytic epoxidation of terpenes: a pathway to bio-based polymers from waste biomass
Epoxides derived from waste biomass are a promising avenue for the production of bio-
based polymers, including polyamides, polyesters, polyurethanes, and polycarbonates. This …
based polymers, including polyamides, polyesters, polyurethanes, and polycarbonates. This …
Anodic production of hydrogen peroxide using commercial carbon materials
D Pangotra, LI Csepei, A Roth, CP de León… - Applied Catalysis B …, 2022 - Elsevier
The electrochemical production of hydrogen peroxide (H 2 O 2) from water is an appealing
alternative to substitute the classic anthraquinone process. Herein, we show a process …
alternative to substitute the classic anthraquinone process. Herein, we show a process …
[HTML][HTML] Energising the E-factor: The E+-factor
The E-factor has become an important measure for the environmental impact of (bio)
chemical reactions. However, summing up the obvious wastes generated in the laboratory …
chemical reactions. However, summing up the obvious wastes generated in the laboratory …
Cascading gC3N4 and Peroxygenases for Selective Oxyfunctionalization Reactions
Peroxygenases are very interesting catalysts for specific oxyfunctionalization chemistry.
Instead of relying on complicated electron transport chains, they rely on simple hydrogen …
Instead of relying on complicated electron transport chains, they rely on simple hydrogen …
Synthesis of biorenewable terpene monomers using enzymatic epoxidation under heterogeneous batch and continuous flow conditions
A commercially available Lipase B from Candida antarctica immobilized onto a
macroporous support (Novozym 435) has been employed in the presence of H2O2 as a …
macroporous support (Novozym 435) has been employed in the presence of H2O2 as a …
Impact of different epoxidation approaches of tall oil fatty acids on rigid polyurethane foam thermal insulation
A Abolins, R Pomilovskis, E Vanags, I Mierina… - Materials, 2021 - mdpi.com
A second-generation bio-based feedstock—tall oil fatty acids—was epoxidised via two
pathways. Oxirane rings were introduced into the fatty acid carbon backbone using a …
pathways. Oxirane rings were introduced into the fatty acid carbon backbone using a …
Natural deep eutectic solvents as multifunctional media for the valorization of agricultural wastes
Y Ma, P Li, Y Li, SJP Willot, W Zhang… - …, 2019 - Wiley Online Library
The use of natural deep eutectic solvents (NADES) as multifunctional solvents for limonene
bioprocessing was reported. NADES were used for the extraction of limonene from orange …
bioprocessing was reported. NADES were used for the extraction of limonene from orange …
Terpenes: A valuable family of compounds for the production of fine chemicals
G Rubulotta, EA Quadrelli - Studies in surface science and catalysis, 2019 - Elsevier
This chapter focuses on monoterpenes, biogenic substrates present in biomass and their
conversion into added-value molecules by chemical reactions such as isomerization …
conversion into added-value molecules by chemical reactions such as isomerization …
Lipase catalyzed self-epoxidation of tall oil fatty acids in batch and continuous flow conditions
E Vanags, A Abolins, U Cabulis - Journal of Polymers and the Environment, 2023 - Springer
Tall oil fatty acids (TOFA) were self-epoxidized by in-situ formed peroxy fatty acids in
solventless conditions. For this purpose, six different lipase enzymes were compared by …
solventless conditions. For this purpose, six different lipase enzymes were compared by …
Improving efficiency and reducing enzyme inactivation during lipase-mediated epoxidation of α-pinene in a double-phase reaction system
L Yu, C Zou, Q Li, Z Liu, Y Liu, A Tang - Bioprocess and Biosystems …, 2023 - Springer
Chemoenzymatic epoxidation of olefin mediated by lipase is a green and environmentally
friendly alternative process. However, the mass transfer barrier and lipase deactivation …
friendly alternative process. However, the mass transfer barrier and lipase deactivation …