Recent advances in catalytic and non-catalytic epoxidation of terpenes: a pathway to bio-based polymers from waste biomass

MFMG Resul, A Rehman, F Saleem, M Usman… - RSC …, 2023 - pubs.rsc.org
Epoxides derived from waste biomass are a promising avenue for the production of bio-
based polymers, including polyamides, polyesters, polyurethanes, and polycarbonates. This …

Anodic production of hydrogen peroxide using commercial carbon materials

D Pangotra, LI Csepei, A Roth, CP de León… - Applied Catalysis B …, 2022 - Elsevier
The electrochemical production of hydrogen peroxide (H 2 O 2) from water is an appealing
alternative to substitute the classic anthraquinone process. Herein, we show a process …

[HTML][HTML] Energising the E-factor: The E+-factor

F Tieves, F Tonin, E Fernández-Fueyo, JM Robbins… - Tetrahedron, 2019 - Elsevier
The E-factor has become an important measure for the environmental impact of (bio)
chemical reactions. However, summing up the obvious wastes generated in the laboratory …

Cascading gC3N4 and Peroxygenases for Selective Oxyfunctionalization Reactions

MMCH Van Schie, W Zhang, F Tieves, DS Choi… - ACS …, 2019 - ACS Publications
Peroxygenases are very interesting catalysts for specific oxyfunctionalization chemistry.
Instead of relying on complicated electron transport chains, they rely on simple hydrogen …

Synthesis of biorenewable terpene monomers using enzymatic epoxidation under heterogeneous batch and continuous flow conditions

A Brandolese, DH Lamparelli… - ACS Sustainable …, 2023 - ACS Publications
A commercially available Lipase B from Candida antarctica immobilized onto a
macroporous support (Novozym 435) has been employed in the presence of H2O2 as a …

Impact of different epoxidation approaches of tall oil fatty acids on rigid polyurethane foam thermal insulation

A Abolins, R Pomilovskis, E Vanags, I Mierina… - Materials, 2021 - mdpi.com
A second-generation bio-based feedstock—tall oil fatty acids—was epoxidised via two
pathways. Oxirane rings were introduced into the fatty acid carbon backbone using a …

Natural deep eutectic solvents as multifunctional media for the valorization of agricultural wastes

Y Ma, P Li, Y Li, SJP Willot, W Zhang… - …, 2019 - Wiley Online Library
The use of natural deep eutectic solvents (NADES) as multifunctional solvents for limonene
bioprocessing was reported. NADES were used for the extraction of limonene from orange …

Terpenes: A valuable family of compounds for the production of fine chemicals

G Rubulotta, EA Quadrelli - Studies in surface science and catalysis, 2019 - Elsevier
This chapter focuses on monoterpenes, biogenic substrates present in biomass and their
conversion into added-value molecules by chemical reactions such as isomerization …

Lipase catalyzed self-epoxidation of tall oil fatty acids in batch and continuous flow conditions

E Vanags, A Abolins, U Cabulis - Journal of Polymers and the Environment, 2023 - Springer
Tall oil fatty acids (TOFA) were self-epoxidized by in-situ formed peroxy fatty acids in
solventless conditions. For this purpose, six different lipase enzymes were compared by …

Improving efficiency and reducing enzyme inactivation during lipase-mediated epoxidation of α-pinene in a double-phase reaction system

L Yu, C Zou, Q Li, Z Liu, Y Liu, A Tang - Bioprocess and Biosystems …, 2023 - Springer
Chemoenzymatic epoxidation of olefin mediated by lipase is a green and environmentally
friendly alternative process. However, the mass transfer barrier and lipase deactivation …