Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis

NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Recent advances in the catalytic synthesis of arylsulfonyl compounds

D Joseph, MA Idris, J Chen, S Lee - ACS Catalysis, 2021 - ACS Publications
Arylsulfonyl compounds are among the most important compounds in pharmaceutical and
medicinal chemistry. Hence, a wide variety of sulfonylation methods have been reported …

Sustainable and practical formation of carbon–carbon and carbon–heteroatom bonds employing organo-alkali metal reagents

LQ Huo, XH Wang, Z Zhang, Z Jia, XS Peng… - Chemical …, 2023 - pubs.rsc.org
Metal-catalysed cross-coupling reactions are amongst the most widely used methods to
directly construct new bonds. In this connection, sustainable and practical protocols …

Divergent reactivity of sulfinates with pyridinium salts based on one-versus two-electron pathways

M Kim, E You, S Park, S Hong - Chemical Science, 2021 - pubs.rsc.org
One of the main goals of modern synthesis is to develop distinct reaction pathways from
identical starting materials for the efficient synthesis of diverse compounds. Herein, we …

Visible-light mediated cross-coupling of aryl halides with sodium sulfinates via carbonyl-photoredox/nickel dual catalysis

S Jiang, ZT Zhang, DJ Young, LL Chai… - Organic Chemistry …, 2022 - pubs.rsc.org
Photoinduced nickel-catalyzed cross-coupling of arylsulfinates (ArSO2−) with (hetero) aryl
halides (Ar′–X) via visible light photoexcitation of 2-chloro-thioxanthen-9-one (Cl-TXO) has …

Evolution of a Green and Sustainable Manufacturing Process for Belzutifan: Part 2─ Development of a Scalable Nickel-Catalyzed Sulfonylation

JC Hethcox, J Kim, HC Johnson, Y Ji… - … Process Research & …, 2024 - ACS Publications
A nickel-catalyzed sulfonylation reaction was discovered and developed into a robust
process for the manufacturing of belzutifan, an FDA-approved treatment for Von Hippel …

A convenient synthesis of sulfones via light promoted coupling of sodium sulfinates and aryl halides

L Chen, J Liang, Z Chen, J Chen… - … Synthesis & Catalysis, 2019 - Wiley Online Library
A convenient and efficient synthesis of sulfones from sulfinates and aryl halides was
developed. The reaction occurred under UV irradiation without transition metal catalyst or …

Nanosized CdS as a reusable photocatalyst: the study of different reaction pathways between tertiary amines and aryl sulfonyl chlorides through visible-light-induced …

S Firoozi, M Hosseini-Sarvari - The Journal of Organic Chemistry, 2021 - ACS Publications
It has been found that the final products of the reaction of sulfonyl chlorides and tertiary
amines in the presence of cadmium sulfide nanoparticles under visible light irradiation are …

Visible Light‐Driven Eosin Y‐Catalyzed Suzuki‐Type Sulfonylation

L Tang, G Lv, F Jia, R Zhao, X Wang… - Advanced Synthesis & …, 2024 - Wiley Online Library
A strategy for sulfonylation of boronic acids with sulfonyl chlorides has been established via
Suzuki‐type radical cross‐coupling. This approach allows for the synthesis of more than 50 …

MOF-Derived subnanometer cobalt catalyst for selective C–H oxidative sulfonylation of tetrahydroquinoxalines with sodium sulfinates

F **e, GP Lu, R **e, QH Chen, HF Jiang… - ACS Catalysis, 2019 - ACS Publications
The development and utilization of reusable base-metal catalysts is a central topic in
catalysis. Herein, via a catalyst design strategy, we present the preparation of a highly …