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Ferroelectricity in molecular solids: a review of electrodynamic properties
In conventional ferroelectrics the polarization is induced either by the relative displacement
of positive and negative ions due to a lattice distortion or by the collective alignment of …
of positive and negative ions due to a lattice distortion or by the collective alignment of …
Molecular donor–acceptor compounds as prospective organic electronics materials
S Horiuchi, T Hasegawa, Y Tokura - … of the Physical Society of Japan, 2006 - journals.jps.jp
The π-electronic functionalities of molecular donor (D)–acceptor (A) compounds have been
attracting subjects for the solid state science as well as for the prospective technological …
attracting subjects for the solid state science as well as for the prospective technological …
Chemical approach to neutral–ionic valence instability, quantum phase transition, and relaxor ferroelectricity in organic charge-transfer complexes
S Horiuchi, R Kumai, Y Okimoto, Y Tokura - Chemical physics, 2006 - Elsevier
Neutral–ionic (NI) phase transition is a reversible switching of organic charge-transfer
complexes between distinct valence states by external stimuli. This phase transformation in …
complexes between distinct valence states by external stimuli. This phase transformation in …
Phenomenology of the neutral-ionic valence instability in mixed stack charge-transfer crystals
Organic charge-transfer (CT) crystals constitute an important class of functional materials,
characterized by the directional charge-transfer interaction between π-electron Donor (D) …
characterized by the directional charge-transfer interaction between π-electron Donor (D) …
Ionic versus electronic ferroelectricity in donor–acceptor molecular sequences
S Horiuchi, K Kobayashi, R Kumai… - Chemistry Letters, 2014 - academic.oup.com
Molecular displacement in an alternating chain of donors and acceptors triggers ferroelectric
switching of large electric polarization with a low electric field in some charge-transfer …
switching of large electric polarization with a low electric field in some charge-transfer …
Static and dynamic order of cooperative multi-electrontransfer
We report on high correlation and ordering of multi-electron transfer at neutral-ionic
transformation in quasi–one-dimensional prototype crystal of tetrathiafulvalene-chloranil …
transformation in quasi–one-dimensional prototype crystal of tetrathiafulvalene-chloranil …
[HTML][HTML] Ultrafast electron and molecular dynamics in photoinduced and electric-field-induced neutral–ionic transitions
Mixed-stacked organic molecular compounds near the neutral–ionic phase boundary,
represented by tetrathiafulvalene-p-chloranil (TTF-CA), show a unique phase transition from …
represented by tetrathiafulvalene-p-chloranil (TTF-CA), show a unique phase transition from …
Short-range ferroelectric order induced by proton transfer-mediated ionicity
Short-range ferroelectric order is postulated to explain unusual one-dimensional dielectric
response in ferroelectric 1, 4-diazabicyclo [2.2. 2] octane. In this pure organic salt, the polar …
response in ferroelectric 1, 4-diazabicyclo [2.2. 2] octane. In this pure organic salt, the polar …
Optimal methods for calculation of the amount of intermolecular electron transfer
In order to determine the optimal methodology for evaluation of the magnitude of
intermolecular charge transfer, several methods have been examined: Mulliken population …
intermolecular charge transfer, several methods have been examined: Mulliken population …
Back to the structural and dynamical properties of neutral-ionic phase transitions
Although the Neutral-Ionic transition in mixed stack charge-transfer crystals was discovered
almost forty years ago, many features of this intriguing phase transition, as well as open …
almost forty years ago, many features of this intriguing phase transition, as well as open …