Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

A machine learning approach to zeolite synthesis enabled by automatic literature data extraction

Z Jensen, E Kim, S Kwon, TZH Gani… - ACS central …, 2019 - ACS Publications
Zeolites are porous, aluminosilicate materials with many industrial and “green” applications.
Despite their industrial relevance, many aspects of zeolite synthesis remain poorly …

The Current Understanding of Mechanistic Pathways in Zeolite Crystallization

AJ Mallette, K Shilpa, JD Rimer - Chemical Reviews, 2024 - ACS Publications
Zeolite catalysts and adsorbents have been an integral part of many commercial processes
and are projected to play a significant role in emerging technologies to address the …

Cooperative and competitive occlusion of organic and inorganic structure-directing agents within chabazite zeolites influences their aluminum arrangement

JR Di Iorio, S Li, CB Jones, CT Nimlos… - Journal of the …, 2020 - ACS Publications
We combine experiment and theory to investigate the cooperation or competition between
organic and inorganic structure-directing agents (SDAs) for occupancy within microporous …

Discovering relationships between OSDAs and zeolites through data mining and generative neural networks

Z Jensen, S Kwon, D Schwalbe-Koda, C Paris… - ACS central …, 2021 - ACS Publications
Organic structure directing agents (OSDAs) play a crucial role in the synthesis of micro-and
mesoporous materials especially in the case of zeolites. Despite the wide use of OSDAs …

Machine learning applied to zeolite synthesis: the missing link for realizing high-throughput discovery

M Moliner, Y Román-Leshkov… - Accounts of chemical …, 2019 - ACS Publications
Conspectus Zeolites are microporous crystalline materials with well-defined cavities and
pores, which can be prepared under different pore topologies and chemical compositions …

Chiral nanoceramics

J Fan, NA Kotov - Advanced Materials, 2020 - Wiley Online Library
The study of different chiral inorganic nanomaterials has been experiencing rapid growth
during the past decade, with its primary focus on metals and semiconductors. Ceramic …

Regulation of the Sulfur Environment in Clusters to Construct a Mn–Sn2S6 Framework for Mercury Bonding

Q Hong, H Xu, J Li, W Huang, Z Qu… - Environmental Science & …, 2022 - ACS Publications
The remarkable chemical activity of metal–sulfur clusters lies in their unique spatial
configuration associated with the abundant unsaturated-coordination nature of sulfur sites …

High-throughput phase elucidation of polycrystalline materials using serial rotation electron diffraction

Y Luo, B Wang, S Smeets, J Sun, W Yang, X Zou - Nature Chemistry, 2023 - nature.com
Rapid phase elucidation of polycrystalline materials is essential for develo** new
materials of chemical, pharmaceutical and industrial interest. Yet, the size and quantity of …