Enol ethers are a fascinating product class and valuable building blocks with versatile
reactivities and synthetic applications. With the emergence of silyl enol ethers, the chemistry …

The cascade functionalizations of alkynes have provided many elegant methods for the
synthesis of useful scaffolds. Amongst these functionalizations, the ones comprising C− C …

We describe the design and development of the first catalytic asymmetric vinylogous Prins
cyclization. This reaction constitutes an efficient approach for highly diastereo-and …

An auxiliary-enabled Pd-catalyzed highly regio-and stereoselective sp3 C–H activation and
the direct arylation of the C3-position of oxygen heterocycles, such as tetrahydrofuran and 1 …

A simple methodology has been developed for the synthesis of substituted
pyrroloisoindolone and pyridoisoindolone via aza-Prins cyclization of endocyclic N …

A new and efficient protocol to prepare indenes is reported. Assisted by boron trifluoride
diethyl etherate, the one-pot reaction of aryl homopropargyl alcohols and aldehydes in the …

TMSOTf-mediated reaction of alkynyl vinylogous carbonates serendipitously gave 1, 4-
oxazepine and dihydropyran dienes via transposition of an ethyl acrylate moiety involving …

The classical Prins cyclization has been one of the most intensively studied reactions during
the last two decades, and it has found many applications in key steps of natural product …

A variety of oxygen, nitrogen and sulfur heterocyclic compounds are synthesized via one-pot
multicomponent Prins, aza-Prins, thia-Prins, oxonium-ene, iminium-ene and thionium-ene …

The copper‐catalyzed intramolecular diastereoselective trifluoromethylcycloetherification of
homoallylic alcohols with Togni's reagent as trifluoromethylating reagent was realized under …