Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

[HTML][HTML] Surface organometallic and coordination chemistry toward single-site heterogeneous catalysts: strategies, methods, structures, and activities

C Coperet, A Comas-Vives, MP Conley… - Chemical …, 2016 - ACS Publications
The chemical industry relies on catalytic processes, which involve mainly heterogeneous
catalysts because they offer many advantages over their homogeneous counterparts such …

Surface organometallic chemistry in heterogeneous catalysis

MK Samantaray, E Pump… - Chemical Society …, 2018 - pubs.rsc.org
The broad challenges of energy and environment have become a main focus of research
efforts to develop more active and selective catalytic systems for key chemical …

Identification and characterization of surface hydroxyl groups by infrared spectroscopy

K Hadjiivanov - Advances in Catalysis, 2014 - Elsevier
Surface hydroxyl groups are active centers in many catalytic reactions and can play an
important role during catalyst preparation. In this chapter, the application of infrared …

Olefin metathesis by supported metal oxide catalysts

S Lwin, IE Wachs - Acs Catalysis, 2014 - ACS Publications
The literature of olefin metathesis by heterogeneous supported catalysts, both industrial-type
supported metal oxides (ReO x/Al2O3, ReO x/(SiO2–Al2O3), MoO x/SiO2, MoO x/Al2O3 …

Combined solid-state NMR, FT-IR and computational studies on layered and porous materials

G Paul, C Bisio, I Braschi, M Cossi, G Gatti… - Chemical Society …, 2018 - pubs.rsc.org
Understanding the structure–property relationship of solids is of utmost relevance for
efficient chemical processes and technological applications in industries. This contribution …

Beyond ordered materials: understanding catalytic sites on amorphous solids

BR Goldsmith, B Peters, JK Johnson, BC Gates… - ACS …, 2017 - ACS Publications
Amorphous materials are widely used as components of solid catalysts and have been the
subject of much applied research. In some instances, their catalytic performance is …

Bio-oils hydrodeoxygenation: Adsorption of phenolic molecules on oxidic catalyst supports

A Popov, E Kondratieva, JM Goupil… - The Journal of …, 2010 - ACS Publications
The interaction of phenol, anisole, and guaiacol, representatives of oxygenate functions
present in pyrolysis bio-oils, with oxides such as silica, alumina (pure or doped with K or F) …

Acid catalysts in industrial hydrocarbon chemistry

G Busca - Chemical Reviews, 2007 - ACS Publications
The hydrocarbon era1 began at the end of the 19th century, as a result of the discovery of oil
fields in the United States and together with the development of internal combustion …

Atomic description of the interface between silica and alumina in aluminosilicates through dynamic nuclear polarization surface-enhanced NMR spectroscopy and first …

M Valla, AJ Rossini, M Caillot, C Chizallet… - Journal of the …, 2015 - ACS Publications
Despite the widespread use of amorphous aluminosilicates (ASA) in various industrial
catalysts, the nature of the interface between silica and alumina and the atomic structure of …