Iodine capture in porous organic polymers and metal–organic frameworks materials

W **e, D Cui, SR Zhang, YH Xu, DL Jiang - Materials Horizons, 2019 - pubs.rsc.org
The enrichment of radioactive iodine in the waste of nuclear industries threatens human
health, and thus the efficient capture of iodine has attracted a great deal of attention in recent …

Magnetic functionalities in MOFs: from the framework to the pore

GM Espallargas, E Coronado - Chemical Society Reviews, 2018 - pubs.rsc.org
In this review, we show the different approaches developed so far to prepare metal–organic
frameworks (MOFs) presenting electronic functionalities, with particular attention to magnetic …

Recent advances in guest effects on spin-crossover behavior in Hofmann-type metal-organic frameworks

ZP Ni, JL Liu, MN Hoque, W Liu, JY Li, YC Chen… - Coordination Chemistry …, 2017 - Elsevier
The incorporation of spin-crossover (SCO) properties into metal-organic frameworks (MOFs)
is an appealing subclass of multifunctional MOFs with potential applications in molecular …

[HTML][HTML] Spin state switching in iron coordination compounds

P Gütlich, AB Gaspar, Y Garcia - Beilstein journal of organic …, 2013 - beilstein-journals.org
The article deals with coordination compounds of iron (II) that may exhibit thermally induced
spin transition, known as spin crossover, depending on the nature of the coordinating ligand …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

On–off switching of a photocatalytic overall reaction through dynamic spin-state transition in a Hofmann clathrate system

GZ Huang, YS **a, F Yang, WJ Long… - Journal of the …, 2023 - ACS Publications
Spin-state transition is a vital factor that dominates catalytic processes, but unveiling its
mechanism still faces the great challenge of the lack of catalyst model systems. Herein, we …

Exploiting redox activity in metal–organic frameworks: concepts, trends and perspectives

DM D'alessandro - Chemical Communications, 2016 - pubs.rsc.org
Of the many thousands of new metal–organic frameworks (MOFs) that are now discovered
each year, many possess potential redox activity arising from the constituent metal ions …

Dynamic magnetic MOFs

E Coronado, GM Espallargas - Chemical Society Reviews, 2013 - pubs.rsc.org
In this review we combine the use of coordination chemistry with the concepts of molecular
magnetism to design magnetic Metal–Organic Frameworks (MOFs) in which the crystalline …

Nanoporous cobalt (II) MOF exhibiting four magnetic ground states and changes in gas sorption upon post-synthetic modification

MH Zeng, Z Yin, YX Tan, WX Zhang… - Journal of the …, 2014 - ACS Publications
We present the syntheses, structural characterization, gas sorption, I2 uptake, and magnetic
properties of a double-walled porous metal–organic framework,[CoII3 (lac) 2 (pybz) 2] …

Combining electron transfer, spin crossover, and redox properties in metal-organic frameworks

L Getzner, D Paliwoda, L Vendier… - Nature …, 2024 - nature.com
Hofmann coordination polymers (CPs) that couple the well-studied spin transition of the FeII
central ion with electron-responsive ligands provide an innovative strategy toward …