Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Porous aromatic frameworks (PAFs) represent an important category of porous solids. PAFs
possess rigid frameworks and exceptionally high surface areas, and, uniquely, they are …

Conspectus The importance of sustainable and green synthetic protocols for the synthesis of
fine chemicals has rapidly increased during the last decades in an effort to reduce the use of …

Pd-catalyzed cross-coupling reactions have become essential tools for the construction of
carbon–carbon and carbon–heteroatom bonds. Over the last three decades, great efforts …

Palladium catalysed cross-couplings reactions have been a dominant method in synthetic
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …

Catalytic cross-coupling reactions of aromatic esters and amides have recently gained
considerable attention from synthetic chemists as de novo and efficient synthetic methods to …

Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

Abstract In 2010, Richard Heck, Ei‐ichi Negishi, and Akira Suzuki joined the prestigious
circle of Nobel Laureate chemists for their roles in discovering and develo** highly …

Methods to functionalize arenes and heteroarenes in a site-selective manner are highly
sought after for rapidly constructing value-added molecules of medicinal, agrochemical, and …

The first now-named Stille reaction was published 38 years ago, and the last comprehensive
revision of this catalysis was in 2004. Since then, the knowledge of the different steps of the …