Molecular electrochemistry of multi-redox functionalized 5-membered heterocycles

D Miesel, A Hildebrandt, H Lang - Current Opinion in Electrochemistry, 2018 - Elsevier
Molecular electrochemistry of multi-redox functionalized 5-membered heterocycles -
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Tuning electronic structure, redox, and photophysical properties in asymmetric NIR-absorbing organometallic BODIPYs

YV Zatsikha, E Maligaspe, AA Purchel… - Inorganic …, 2015 - ACS Publications
Stepwise modification of the methyl groups at the α positions of BODIPY 1 was used for
preparation of a series of mono-(2, 4, and 6) and diferrocene (3) substituted donor–acceptor …

Synthesis and charge-transfer dynamics in a ferrocene-containing organoboryl aza-BODIPY donor–acceptor triad with boron as the hub

E Maligaspe, TJ Pundsack, LM Albert… - Inorganic …, 2015 - ACS Publications
AN, N′-bis (ferroceneacetylene) boryl complex of 3, 3′-diphenylazadiisoindolylmethene
was synthesized by the reaction of an N, N′-difluoroboryl complex of 3, 3 …

Synthesis, redox properties, and electronic coupling in the diferrocene aza-dipyrromethene and azaBODIPY donor–acceptor dyad with direct ferrocene− α-pyrrole …

CJ Ziegler, K Chanawanno, A Hasheminsasab… - Inorganic …, 2014 - ACS Publications
3, 3′-Diferrocenylazadipyrromethene (3) and corresponding difluoroboryl (azaBODIPY)
complex (4) were synthesized in several steps from ferrocenecarbaldehyde, following the …

Electronic Properties of Mono‐Substituted Tetraferrocenyl Porphyrins in Solution and on a Gold Surface: Assessment of the Influencing Factors for …

A Vecchi, NR Erickson, JR Sabin… - … A European Journal, 2015 - Wiley Online Library
Two unsymmetric meso‐tetraferrocenyl‐containing porphyrins of general formula Fc3
(FcCOR) Por (Fc= ferrocenyl, R= CH3 or (CH2) 5Br, Por= porphyrin) were prepared and …

Synthesis, characterization, electrochemistry, and computational studies of ferrocenyl-substituted siloles

SW Lehrich, A Hildebrandt, T Rüffer, M Korb… - …, 2014 - ACS Publications
Ferrocenylsiloles of the type 2, 5-Fc2-3, 4-Ph2-c C4SiR2 (3a, R= Me; 3b, R= Ph) have been
prepared by reductive cyclization from diethynylsilanes, followed by ferrocenylation using …

Redox and photoinduced electron-transfer properties in short distance organoboryl ferrocene-subphthalocyanine dyads

E Maligaspe, MR Hauwiller, YV Zatsikha… - Inorganic …, 2014 - ACS Publications
Reaction between ferrocene lithium or ethynylferrocene magnesium bromide and (chloro)
boronsubphthalocyanine leads to formation of ferrocene-(2) and ethynylferrocene-(3) …

Probing electronic communications in heterotrinuclear Fe–Ru–Fe molecular wires formed by ruthenium (II) tetraphenylporphyrin and isocyanoferrocene or 1, 1 …

VN Nemykin, SV Dudkin, M Fathi-Rasekh… - Inorganic …, 2015 - ACS Publications
Two new heterotrinuclear Fe–Ru–Fe complexes of ruthenium (II) tetraphenylporphyrin
axially coordinated with a pair of isocyanoferrocene ((FcNC) 2RuTPP, 1) or 1, 1 …

Five-membered heterocycles as linking units in strongly coupled homobimetallic group 8 metal half-sandwich complexes

U Pfaff, A Hildebrandt, M Korb, D Schaarschmidt… - …, 2015 - ACS Publications
The synthesis and characterization of a series of alkynyl half-sandwich complexes of type 2,
5-((η5-C5H5)(dppe) MC C) 2-c C4H2E (E= O (11), S (12); M= Fe (a), Ru (b); dppe= 1, 2-bis …

Electronic modification of redox active ferrocenyl termini and their influence on the electrontransfer properties of 2, 5-diferrocenyl-N-phenyl-1H-pyrroles

SW Lehrich, A Hildebrandt, M Korb, H Lang - Journal of Organometallic …, 2015 - Elsevier
Abstract A series of 2, 5-diferrocenyl-N-phenyl-1H-pyrroles of type 2, 5-Fc 2-c C 4 H 2 NPh
(Fc= Fe (η 5-C 5 H 4)(η 5-C 5 H 4 R); 3a, R= c C 4 H 7 O 2; 3b, H; 3c, 3, 5-(CF 3) 2-C 6 H 3) …