Understanding MOF flexibility: An analysis focused on pillared layer MOFs as a model system
Flexible porous frameworks are at the forefront of materials research. A unique feature is
their ability to open and close their pores in an adaptive manner induced by chemical and …
their ability to open and close their pores in an adaptive manner induced by chemical and …
Chemistry of soft porous crystals: structural dynamics and gas adsorption properties
In this Minireview, we discuss the fundamental chemistry of soft porous crystals (SPCs) by
characterizing their common structural features and the resulting structural softness and …
characterizing their common structural features and the resulting structural softness and …
Flexible metal–organic frameworks for gas storage and separation
Flexible metal–organic frameworks (MOFs) have gradually attracted much attention due to
their reversible structural changes and flexible structural responses. The basic research of …
their reversible structural changes and flexible structural responses. The basic research of …
Elucidation of flexible metal-organic frameworks: Research progresses and recent developments
Flexibility is a unique property of metal-organic frameworks (MOFs) that differentiates them
from other rigid inorganic porous materials such as zeolites and porous silica. Flexible …
from other rigid inorganic porous materials such as zeolites and porous silica. Flexible …
Isotope-selective pore opening in a flexible metal-organic framework
Flexible metal-organic frameworks that show reversible guest-induced phase transitions
between closed and open pore phases have enormous potential for highly selective, energy …
between closed and open pore phases have enormous potential for highly selective, energy …
Reversible switching between highly porous and nonporous phases of an interpenetrated diamondoid coordination network that exhibits gate‐opening at methane …
Herein, we report that a new flexible coordination network, NiL2 (L= 4‐(4‐pyridyl)‐biphenyl‐
4‐carboxylic acid), with diamondoid topology switches between non‐porous (closed) and …
4‐carboxylic acid), with diamondoid topology switches between non‐porous (closed) and …
Gating effect for gas adsorption in microporous materials—mechanisms and applications
In the past two decades, various microporous materials have been developed as useful
adsorbents for gas adsorption for a wide range of industries. Considerable efforts have been …
adsorbents for gas adsorption for a wide range of industries. Considerable efforts have been …
Multi-dimensional metal-organic frameworks based on mixed linkers: Interplay between structural flexibility and functionality
Metal-organic frameworks (MOFs) are regarded widely because of their intriguing structural
dynamism, which sets them apart from other porous materials. Such structural flexibility or …
dynamism, which sets them apart from other porous materials. Such structural flexibility or …
Unraveling structure and dynamics in porous frameworks via advanced in situ characterization techniques
Dynamic metal–organic frameworks (MOFs) represent a subgroup of frameworks featuring
unique performance, as they are capable of adapting their pore size and/or the orientation of …
unique performance, as they are capable of adapting their pore size and/or the orientation of …
Spatiotemporal Design of the Metal–Organic Framework DUT‐8 (M)
Switchable metal–organic frameworks (MOFs) change their structure in time and selectively
open their pores adsorbing guest molecules, leading to highly selective separation …
open their pores adsorbing guest molecules, leading to highly selective separation …