Advances in sulfur chemistry for treatment of acid gases

AK Gupta, S Ibrahim, A Al Shoaibi - Progress in Energy and Combustion …, 2016 - Elsevier
Increased energy demand worldwide has caused faster depletion of sweet feedstock and
increased exploitation of sourer hydrocarbon fuels. These fuels often contain acid gases (H …

Prediction of thermodynamic properties for sulfur dimer

QC Ding, CS Jia, JZ Liu, J Li, RF Du, JY Liu… - Chemical Physics …, 2022 - Elsevier
We present new explicit representations with temperature and pressure as independent
variables for the Gibbs free energy and entropy of S 2. The developed representations only …

An Exploratory Flow Reactor Study of H2S Oxidation at 30–100 Bar

Y Song, H Hashemi, JM Christensen… - … Journal of Chemical …, 2017 - Wiley Online Library
Hydrogen sulfide oxidation experiments were conducted in O2/N2 at high pressure (30 and
100 bar) under oxidizing and stoichiometric conditions. Temperatures ranged from 450 to …

Shock-tube water time-histories and ignition delay time measurements for H2S near atmospheric pressure

O Mathieu, C Mulvihill, EL Petersen - Proceedings of the Combustion …, 2017 - Elsevier
Hydrogen sulfide combustion has been of interest in recent years due to its presence in coal-
derived syngas and in sour gas. However, there are limited data available for the calibration …

Oxy-fuel combustion of lean acid gas for high sulfur recovery efficiency based on straight-through claus process

X Tao, X Yu, S Guo, F Zhou, Y Gao, L Ding… - Gas Science and …, 2023 - Elsevier
Present methods mainly adopt air as an oxidizer for recovering sulfur from lean acid gas, the
presence of N 2 is detrimental to the combustion of lean acid gas. In this study, oxy-fuel …

[HTML][HTML] Combustion chemistry of COS and occurrence of intersystem crossing

Z Zeng, BZ Dlugogorski, I Oluwoye, M Altarawneh - Fuel, 2021 - Elsevier
This contribution combines results of experiments with kinetic modelling to probe the
unusual behaviour of carbonyl sulfide (COS), a sulfur species that frequently arises in fuel …

Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling

X Tao, F Zhou, X Yu, S Guo, Y Gao, L Ding, G Yu… - Chinese Journal of …, 2023 - Elsevier
CO 2 is an important component in the acid gas and it is necessary to study the effect of CO
2 presence on the oxy-fuel combustion of H 2 S with particular focus on the formation of …

Detailed kinetic modelling of H2S oxidation with presence of CO2 under rich condition

Y Li, X Yu, H Li, Q Guo, Z Dai, G Yu, F Wang - Applied Energy, 2017 - Elsevier
This paper presents a detailed kinetic study of H 2 S oxidation with presence of CO 2 under
fuel rich condition. Effect of CO 2 reactivity on the partial oxidation of H 2 S was particularly …

Xylene addition effects to H2S combustion under Claus condition

S Ibrahim, A Al Shoaibi, AK Gupta - Fuel, 2015 - Elsevier
Experimental results are presented on the combustion of H 2 S and mixtures of H 2 S and
xylene at an equivalence ratio of three (Claus condition). The H 2 S mole fraction decreased …

Experimental examination of syngas recovery from acid gases

AM El-Melih, S Ibrahim, AK Gupta, A Al Shoaibi - Applied Energy, 2016 - Elsevier
This paper shows the potential for valuable syngas (H 2 and CO) production from a
laboratory-scale reactor, as an alternative and viable means for the treatment of acid gas (H …