Advances in sulfur chemistry for treatment of acid gases
Increased energy demand worldwide has caused faster depletion of sweet feedstock and
increased exploitation of sourer hydrocarbon fuels. These fuels often contain acid gases (H …
increased exploitation of sourer hydrocarbon fuels. These fuels often contain acid gases (H …
Prediction of thermodynamic properties for sulfur dimer
QC Ding, CS Jia, JZ Liu, J Li, RF Du, JY Liu… - Chemical Physics …, 2022 - Elsevier
We present new explicit representations with temperature and pressure as independent
variables for the Gibbs free energy and entropy of S 2. The developed representations only …
variables for the Gibbs free energy and entropy of S 2. The developed representations only …
An Exploratory Flow Reactor Study of H2S Oxidation at 30–100 Bar
Y Song, H Hashemi, JM Christensen… - … Journal of Chemical …, 2017 - Wiley Online Library
Hydrogen sulfide oxidation experiments were conducted in O2/N2 at high pressure (30 and
100 bar) under oxidizing and stoichiometric conditions. Temperatures ranged from 450 to …
100 bar) under oxidizing and stoichiometric conditions. Temperatures ranged from 450 to …
Shock-tube water time-histories and ignition delay time measurements for H2S near atmospheric pressure
Hydrogen sulfide combustion has been of interest in recent years due to its presence in coal-
derived syngas and in sour gas. However, there are limited data available for the calibration …
derived syngas and in sour gas. However, there are limited data available for the calibration …
Oxy-fuel combustion of lean acid gas for high sulfur recovery efficiency based on straight-through claus process
X Tao, X Yu, S Guo, F Zhou, Y Gao, L Ding… - Gas Science and …, 2023 - Elsevier
Present methods mainly adopt air as an oxidizer for recovering sulfur from lean acid gas, the
presence of N 2 is detrimental to the combustion of lean acid gas. In this study, oxy-fuel …
presence of N 2 is detrimental to the combustion of lean acid gas. In this study, oxy-fuel …
[HTML][HTML] Combustion chemistry of COS and occurrence of intersystem crossing
This contribution combines results of experiments with kinetic modelling to probe the
unusual behaviour of carbonyl sulfide (COS), a sulfur species that frequently arises in fuel …
unusual behaviour of carbonyl sulfide (COS), a sulfur species that frequently arises in fuel …
Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling
X Tao, F Zhou, X Yu, S Guo, Y Gao, L Ding, G Yu… - Chinese Journal of …, 2023 - Elsevier
CO 2 is an important component in the acid gas and it is necessary to study the effect of CO
2 presence on the oxy-fuel combustion of H 2 S with particular focus on the formation of …
2 presence on the oxy-fuel combustion of H 2 S with particular focus on the formation of …
Detailed kinetic modelling of H2S oxidation with presence of CO2 under rich condition
Y Li, X Yu, H Li, Q Guo, Z Dai, G Yu, F Wang - Applied Energy, 2017 - Elsevier
This paper presents a detailed kinetic study of H 2 S oxidation with presence of CO 2 under
fuel rich condition. Effect of CO 2 reactivity on the partial oxidation of H 2 S was particularly …
fuel rich condition. Effect of CO 2 reactivity on the partial oxidation of H 2 S was particularly …
Xylene addition effects to H2S combustion under Claus condition
Experimental results are presented on the combustion of H 2 S and mixtures of H 2 S and
xylene at an equivalence ratio of three (Claus condition). The H 2 S mole fraction decreased …
xylene at an equivalence ratio of three (Claus condition). The H 2 S mole fraction decreased …
Experimental examination of syngas recovery from acid gases
This paper shows the potential for valuable syngas (H 2 and CO) production from a
laboratory-scale reactor, as an alternative and viable means for the treatment of acid gas (H …
laboratory-scale reactor, as an alternative and viable means for the treatment of acid gas (H …