Water‐soluble polymers with appending porphyrins as bioinspired catalysts for the hydrogen evolution reaction

L **e, J Tian, Y Ouyang, X Guo… - Angewandte Chemie …, 2020 - Wiley Online Library
Molecular design to improve catalyst performance is significant but challenging. In enzymes,
residue groups that are close to reaction centers play critical roles in regulating activities …

Mechanistic Insights Into Iron(II) Bis(pyridyl)amine‐Bipyridine Skeleton for Selective CO2 Photoreduction

XZ Wang, SL Meng, JY Chen, HX Wang… - Angewandte Chemie …, 2021 - Wiley Online Library
A bis (pyridyl) amine‐bipyridine‐iron (II) framework (Fe (BPAbipy)) of complexes 1–3 is
reported to shed light on the multistep nature of CO2 reduction. Herein, photocatalytic …

Dual electronic effects achieving a high-performance Ni(II) pincer catalyst for CO2 photoreduction in a noble-metal-free system

HH Huang, JH Zhang, M Dai, L Liu, Z Ye, J Liu… - Proceedings of the …, 2022 - pnas.org
A carbazolide-bis (NHC) NiII catalyst (1; NHC, N-heterocyclic carbene) for selective CO2
photoreduction was designed herein by a one-stone-two-birds strategy. The extended π …

Electricity-driven recycling of ester plastics using one-electron electro-organocatalysis

PH Pham, S Barlow, SR Marder, OR Luca - Chem Catalysis, 2023 - cell.com
We report the catalytic use of electrochemically generated one-electron reducing agents to
produce ester anion radicals that can decompose to acids and alcohols in the presence of …

Manganese N-heterocyclic carbene pincers for the electrocatalytic reduction of carbon dioxide

THT Myren, AM Lilio, CG Huntzinger… - …, 2018 - ACS Publications
We report the synthesis, characterization, and catalytic CO2 reduction activity of two LMn
(CO) 3Br complexes with carbene-pyridine-carbene pincer ligands,[MnCNCMe] Br 1 and …

Identifying a Real Catalyst of [NiFe]‐Hydrogenase Mimic for Exceptional H2 Photogeneration

XZ Wang, SL Meng, H **ao, K Feng… - Angewandte …, 2020 - Wiley Online Library
Inspired by the natural [NiFe]‐H2ase, we designed mimic 1,(dppe) Ni (μ‐pdt)(μ‐Cl) Ru (CO)
2Cl to realize effective H2 evolution under photocatalytic conditions. However, a new …

Mechanistic insights into consecutive 2e− and 2H+ reactions of hydrogenase mimic

XZ Wang, SL Meng, J Liu, C Yu, C Ye, HX Wang… - Chem, 2023 - cell.com
The [NiFe] heterobinuclear hydrogenase active site in nature is responsible for a typical 2e−
and 2H+ transformation with extraordinarily efficient H 2 evolution. However, the difficulty in …

Divide and Conquer: Desymmetrization Separates Charge and Mass Transport in Porphyrinic Covalent Organic Frameworks for Artificial Photosynthesis

Y Wang, YH Zhong, YD Wang, Y Ma, XY Gao… - CCS …, 2024 - chinesechemsoc.org
Material advances over the past decades in the recapitulation of natural photosystems have
given rise to a series of functional covalent organic frameworks (COFs) for accelerating …

[HTML][HTML] Au24Cd Nanoenzyme Coating for Enhancing Electrochemical Sensing Performance of Metal Wire Microelectrodes

JY Chen, S Huang, SJ Liu, ZJ Liu, XY Xu, MY He… - Biosensors, 2024 - mdpi.com
Dopamine (DA), ascorbic acid (AA), and uric acid (UA) are crucial neurochemicals, and their
abnormal levels are involved in various neurological disorders. While electrodes for their …

[HTML][HTML] Redox-Active Manganese Pincers for Electrocatalytic CO2 Reduction

HA Petersen, THT Myren, OR Luca - Inorganics, 2020 - mdpi.com
The decrease of total amount of atmospheric CO2 is an important societal challenge in
which CO2 reduction has an important role to play. Electrocatalytic CO2 reduction with …