Supramolecular helical systems: helical assemblies of small molecules, foldamers, and polymers with chiral amplification and their functions

E Yashima, N Ousaka, D Taura, K Shimomura… - Chemical …, 2016 - ACS Publications
In this review, we describe the recent advances in supramolecular helical assemblies
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …

Functional naphthalene diimides: synthesis, properties, and applications

M Al Kobaisi, SV Bhosale, K Latham… - Chemical …, 2016 - ACS Publications
This comprehensive review surveys developments over the past decade in the field of
naphthalene diimides (NDIs). It explores their application toward: supramolecular chemistry; …

Hierarchical self-assembly into chiral nanostructures

Y Sang, M Liu - Chemical Science, 2022 - pubs.rsc.org
One basic principle regulating self-assembly is associated with the asymmetry of constituent
building blocks or packing models. Using asymmetry to manipulate molecular-level devices …

Self-sorted, random, and block supramolecular copolymers via sequence controlled, multicomponent self-assembly

A Sarkar, R Sasmal, C Empereur-Mot… - Journal of the …, 2020 - ACS Publications
Multicomponent supramolecular copolymerization promises to construct complex
nanostructures with emergent properties. However, even with two monomeric components …

Pathway Control of π‐Conjugated Supramolecular Polymers by Incorporating Donor‐Acceptor Functionality

F Wang, R Liao, F Wang - Angewandte Chemie, 2023 - Wiley Online Library
Controlling the nanoscale orientation of π‐conjugated systems remains challenging due to
the complexity of multiple energy landscapes involved in the supramolecular assembly …

Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization

E Weyandt, L Leanza, R Capelli, GM Pavan… - Nature …, 2022 - nature.com
Multi-component systems often display convoluted behavior, pathway complexity and
coupled equilibria. In recent years, several ways to control complex systems by manipulating …

Amplification of dissymmetry for circularly polarized photodetection by cooperative supramolecular polymerization

Y Xue, C Zhang, T Lv, L Qiu, F Wang - Angewandte Chemie, 2023 - Wiley Online Library
Circularly polarized photodetectors require chiral light absorption materials with high
sensing efficiency and low costs. Here readily accessible point chirality has been introduced …

Controlled noncovalent synthesis of secondary supramolecular polymers

S Sarkar, R Laishram, D Deb… - Journal of the American …, 2023 - ACS Publications
Dynamic supramolecular polymers, with their functional similarities to classical covalent
polymers and their adaptive and self-repairing nature reminiscent of biological assemblies …

Stereoselective primary and secondary nucleation events in multicomponent seeded supramolecular polymerization

S Sarkar, A Sarkar, A Som, SS Agasti… - Journal of the American …, 2021 - ACS Publications
Bioinspired, kinetically controlled seeded growth has been recently shown to provide length,
dispersity, and sequence control on the primary structure of dynamic supramolecular …

Chiral arylene diimide phosphors: circularly polarized ambient phosphorescence from bischromophoric pyromellitic diimides

S Garain, S Sarkar, B Chandra Garain… - Angewandte Chemie …, 2022 - Wiley Online Library
Chiral organic phosphors with circularly polarized room‐temperature phosphorescence
(CPP) provide new prospects to the realm of circularly polarized luminescence (CPL) …