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Design of molecular water oxidation catalysts with earth-abundant metal ions
M Kondo, H Tatewaki, S Masaoka - Chemical Society Reviews, 2021 - pubs.rsc.org
The four-electron oxidation of water (2H2O→ O2+ 4H++ 4e−) is considered the main
bottleneck in artificial photosynthesis. In nature, this reaction is catalysed by a Mn4CaO5 …
bottleneck in artificial photosynthesis. In nature, this reaction is catalysed by a Mn4CaO5 …
Water oxidation using earth-abundant transition metal catalysts: opportunities and challenges
Catalysts for the oxidation of H2O are an integral component of solar energy to fuel
conversion technologies. Although catalysts based on scarce and precious metals have …
conversion technologies. Although catalysts based on scarce and precious metals have …
Unified structural motifs of the catalytically active state of Co (oxyhydr) oxides during the electrochemical oxygen evolution reaction
Efficient catalysts for the anodic oxygen evolution reaction (OER) are critical for
electrochemical H2 production. Their design requires structural knowledge of their …
electrochemical H2 production. Their design requires structural knowledge of their …
Electrocatalytic Oxygen Reduction Reaction of Peripheral Functionalized Cobalt Porphyrins (2.1. 2.1)
Y Dong, X Lv, Y Sun, Q Zhao, H Lei, F Wu… - Inorganic …, 2024 - ACS Publications
Two peripheral functionalized clamp-shaped cobalt porphyrin (2.1. 2.1) complexes were
synthesized, and their electrocatalytic ORR abilities were investigated. The crystal data and …
synthesized, and their electrocatalytic ORR abilities were investigated. The crystal data and …
Enhanced oxygen evolution over dual corner-shared cobalt tetrahedra
Develo** efficient catalysts is of paramount importance to oxygen evolution, a sluggish
anodic reaction that provides essential electrons and protons for various electrochemical …
anodic reaction that provides essential electrons and protons for various electrochemical …
Mechanistic investigations of water oxidation by a molecular cobalt oxide analogue: Evidence for a highly oxidized intermediate and exclusive terminal oxo …
Artificial photosynthesis (AP) promises to replace society's dependence on fossil energy
resources via conversion of sunlight into sustainable, carbon-neutral fuels. However, large …
resources via conversion of sunlight into sustainable, carbon-neutral fuels. However, large …
{Co4O4} and {CoxNi4–xO4} Cubane Water Oxidation Catalysts as Surface Cut-Outs of Cobalt Oxides
The future of artificial photosynthesis depends on economic and robust water oxidation
catalysts (WOCs). Cobalt-based WOCs are especially promising for knowledge transfer …
catalysts (WOCs). Cobalt-based WOCs are especially promising for knowledge transfer …
Surface Proton Hop** and Fast-Kinetics Pathway of Water Oxidation on Co3O4 (001) Surface
We propose a mechanism of water splitting on cobalt oxide surface with atomistic
thermodynamic and kinetic details. The density-functional theory studies suggest that the …
thermodynamic and kinetic details. The density-functional theory studies suggest that the …
Bioinspired molecular clusters for water oxidation
Abstract Water oxidation (2 H 2 O→ 4H++ 4 e-+ O 2) is a key step in utilization of solar
energy for producing hydrogen of artificial photosynthetic system. Inspired by the oxygen …
energy for producing hydrogen of artificial photosynthetic system. Inspired by the oxygen …
Mechanistic aspects of cobalt–oxo cubane clusters in oxidation chemistry
Cobalt oxides are recognized as one of the most efficient earth-abundant catalysts for
challenging oxidation chemistry, with substrates ranging from water to organic compounds …
challenging oxidation chemistry, with substrates ranging from water to organic compounds …