Exploring multidimensional chemical spaces: Instrumentation and chemical systems for the parallelization of hydrogen evolving photocatalytic reactions
EM Lopato, S Bernhard - Energy & Fuels, 2021 - ACS Publications
Photocatalytic hydrogen (H2) evolution, particularly though water reduction, presents an
enticing alternative to current fossil fuel intensive methods of hydrogen production. While …
enticing alternative to current fossil fuel intensive methods of hydrogen production. While …
Analysis of a photochemical water splitting reactor with supramolecular catalysts and a proton exchange membrane
In this paper, a new type of photochemical water splitting system is proposed and analyzed.
The system comprises two reactors in which photocatalytic half-reactions of water reduction …
The system comprises two reactors in which photocatalytic half-reactions of water reduction …
Synthesis, characterization, and study of the photophysics and photocatalytic properties of the photoinitiated electron collector [{(phen) 2Ru (dpp)} 2RhBr2](PF6) 5
The heterometallic photoinitiated electron collector [{(phen) 2Ru (dpp)} 2RhBr2](PF6) 5
(phen= 1, 10-phenanthroline, dpp= 2, 3-bis (2-pyridyl) pyrazine) has been synthesized and …
(phen= 1, 10-phenanthroline, dpp= 2, 3-bis (2-pyridyl) pyrazine) has been synthesized and …
A series of supramolecular complexes for solar energy conversion via water reduction to produce hydrogen: an excited state kinetic analysis of Ru (II), Rh (III), Ru (II) …
Mixed-metal supramolecular complexes have been designed that photochemically absorb
solar light, undergo photoinitiated electron collection and reduce water to produce hydrogen …
solar light, undergo photoinitiated electron collection and reduce water to produce hydrogen …
Nonchromophoric halide ligand variation in polyazine-bridged Ru (II), Rh (III) bimetallic supramolecules offering new insight into photocatalytic hydrogen production …
HM Rogers, TA White, BN Stone… - Inorganic …, 2015 - ACS Publications
The new bimetallic complex [(Ph2phen) 2Ru (dpp) RhBr2 (Ph2phen)](PF6) 3 (1)(Ph2phen=
4, 7-diphenyl-1, 10-phenanthroline; dpp= 2, 3-bis (2-pyridyl) pyrazine) was synthesized and …
4, 7-diphenyl-1, 10-phenanthroline; dpp= 2, 3-bis (2-pyridyl) pyrazine) was synthesized and …
Molecular charge transfer and quantum efficiency analyses of a photochemical reactor for hydrogen production
This paper examines a lab-scale, batch-type photochemical reactor design for hydrogen
generation from water. The reactor comprises a transparent cylindrical reaction vessel of …
generation from water. The reactor comprises a transparent cylindrical reaction vessel of …
Increased photocatalytic activity in Ru (II), Rh (III) supramolecular bimetallic complexes with terminal ligand substitution
Abstract Three new Ru (II), Rh (III) supramolecular bimetallic complexes of the design [(Ph 2
phen) 2 Ru (dpp) RhCl 2 (R 2-bpy)](PF 6) 3 (R= CH 3 (Ru-Rh (Me 2 bpy)), H (Ru-Rh (bpy)) …
phen) 2 Ru (dpp) RhCl 2 (R 2-bpy)](PF 6) 3 (R= CH 3 (Ru-Rh (Me 2 bpy)), H (Ru-Rh (bpy)) …
Supramolecular complexes as photoinitiated electron collectors: applications in solar hydrogen production
The conversion of light energy into chemical energy is a focus of much research. Solar
energy is of sufficient energy to drive water splitting to generate hydrogen and oxygen. The …
energy is of sufficient energy to drive water splitting to generate hydrogen and oxygen. The …
Design and Modification of Polyazine-Bridged Ru (II), Rh (III) Bimetallic and Trimetallic Supramolecular Complexes Applicable in Solar Energy Harvesting for the …
TA White - 2012 - vtechworks.lib.vt.edu
The goal of this research was to develop a series of mixed-metal supramolecular complexes
through systematic component variation to better understand the role of structural …
through systematic component variation to better understand the role of structural …
Synthesis and Study of Polyazine Bridged Mixed Metal Dyads: Electrochemical, Photophysical, and Photochemical Properties of a New Supramolecular Architecture
DF Zigler - 2008 - vtechworks.lib.vt.edu
A series mixed metal supramolecular complexes were synthesized and studied by
electrochemistry, photophysics and photochemistry. The complexes consisted of a single …
electrochemistry, photophysics and photochemistry. The complexes consisted of a single …