Fe (II) redox chemistry in the environment

J Huang, A Jones, TD Waite, Y Chen, X Huang… - Chemical …, 2021 - ACS Publications
Iron (Fe) is the fourth most abundant element in the earth's crust and plays important roles in
both biological and chemical processes. The redox reactivity of various Fe (II) forms has …

[HTML][HTML] Mineral-mediated stability of organic carbon in soil and relevant interaction mechanisms

Z Xu, DCW Tsang - Eco-Environment & Health, 2024 - Elsevier
Soil, the largest terrestrial carbon reservoir, is central to climate change and relevant
feedback to environmental health. Minerals are the essential components that contribute to …

Multiple effects of humic components on microbially mediated iron redox processes and production of hydroxyl radicals

R Han, Z Wang, J Lv, Z Zhu, GH Yu, G Li… - … Science & Technology, 2022 - ACS Publications
Microbially mediated iron redox processes are of great significance in the biogeochemical
cycles of elements, which are often coupled with soil organic matter (SOM) in the …

Fe (II)-catalyzed transformation of ferrihydrite with different degrees of crystallinity

Y Liu, Y Ding, A Sheng, X Li, J Chen… - … Science & Technology, 2023 - ACS Publications
Natural occurring ferrihydrite (Fh) nanoparticles have varying degrees of crystallinity, but
how Fh crystallinity affects its transformation behavior remains elusive. Here, we …

Reductive sequestration of Cr (VI) and immobilization of C during the microbially mediated transformation of Ferrihydrite-Cr (VI)-fulvic acid coprecipitates

S Hu, H Zhang, Y Yang, W Wang, W Zhou… - Environmental …, 2023 - ACS Publications
Cr (VI) detoxification and organic matter (OM) stabilization are usually influenced by the
biological transformation of iron (Fe) minerals; however, the underlying mechanisms of …

Impact of organic matter on iron (II)-catalyzed mineral transformations in ferrihydrite–organic matter coprecipitates

LK ThomasArrigo, JM Byrne, A Kappler… - … science & technology, 2018 - ACS Publications
Poorly crystalline Fe (III)(oxyhydr) oxides like ferrihydrite are abundant in soils and
sediments and are often associated with organic matter (OM) in the form of mineral-organic …

Understanding the importance of labile Fe (III) during Fe (II)-catalyzed transformation of metastable iron oxyhydroxides

J Liu, A Sheng, X Li, Y Arai, Y Ding, M Nie… - Environmental …, 2022 - ACS Publications
Transformation of metastable Fe (III) oxyhydroxides is a prominent process in natural
environments and can be significantly accelerated by the coexisting aqueous Fe (II)(Fe (II) …

Elucidating the redox-driven dynamic interactions between arsenic and iron-impregnated biochar in a paddy soil using geochemical and spectroscopic techniques

X Yang, SM Shaheen, J Wang, D Hou, YS Ok… - Journal of hazardous …, 2022 - Elsevier
Abstract Iron (Fe)-modified biochar, a renewable amendment that synthetizes the functions
of biochar and Fe materials, demonstrates a potential to remediate arsenic (As) …

Citrate controls Fe (II)-catalyzed transformation of ferrihydrite by complexation of the labile Fe (III) intermediate

A Sheng, X Li, Y Arai, Y Ding… - … Science & Technology, 2020 - ACS Publications
Ferrihydrite (Fh) is generally associated with dissolved organic matter (DOM) in natural
environments due to a strong sorption affinity at circumneutral pH and its high specific …

Labile Fe (III) from sorbed Fe (II) oxidation is the key intermediate in Fe (II)-catalyzed ferrihydrite transformation

A Sheng, J Liu, X Li, O Qafoku, RN Collins… - … et Cosmochimica Acta, 2020 - Elsevier
Ferrihydrite (Fh) is a major Fe (III)-(oxyhydr) oxide nanomineral distinguished by its poor
crystallinity and thermodynamic metastability. While it is well known that in suboxic …