Approaching 25 years since its invention, atom transfer radical polymerization (ATRP) is
established as a powerful technique to prepare precisely defined polymeric materials. This …

The discovery, in the mid 1990s, that certain cobalt, ruthenium and copper complexes could
effectively control the radical polymerization of a number of polar olefins, allowing for the …

Organocobalt (III) complexes (R-CoIII), defined as cobalt complexes featuring a carbon–
cobalt bond, are largely used to produce carbon-centered radicals by homolytic cleavage of …

Controlled radical polymerization (CRP) techniques offer the opportunity to properly design
polymer chains and adjust their chemical and physical properties. Among these techniques …

Controlled radical polymerization has become increasingly important over the past decade
and a half, allowing for the facile synthesis of specific macromolecular architectures with …

Poly (N‐vinylcaprolactam)(PNVCL) is a thermoresponsive and biocompatible polymer that
raises an increasing interest in the biomedical area, especially in drug delivery systems …

The effects of photoirradiation in controlled and living radical polymerization (LRP), namely
nitroxide-mediated polymerization (NMP), atom-transfer radical polymerization (ATRP) …

Metal-mediated reversible deactivation radical polymerization (RDRP) is now a cornerstone
of functional polymer synthesis, dominated by copper complexes and the Atom Transfer …

The copolymerization of ethylene with polar monomers is a major challenge when it comes
to the manufacture of materials with potential for a wide range of commercial applications. In …

This review focuses on an emerging class of controlled radical polymerization named
Organometallic-Mediated Radical Polymerization (OMRP). The latter is based on the …