The renaissance of non‐aqueous uranium chemistry
ST Liddle - Angewandte Chemie International Edition, 2015 - Wiley Online Library
Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …
Solution and solid-state structural chemistry of actinide hydrates and their hydrolysis and condensation products
Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and
Condensation Products | Chemical Reviews ACS ACS Publications C&EN CAS Find my …
Condensation Products | Chemical Reviews ACS ACS Publications C&EN CAS Find my …
Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [UVIO2]2+
The uranyl ion,[UVIO2] 2+, possesses rigorously trans, strongly covalent, and chemically
robust U-oxo groups. However, through the use of anaerobic reaction techniques, both one …
robust U-oxo groups. However, through the use of anaerobic reaction techniques, both one …
Recent developments in synthesis and structural chemistry of nonaqueous actinide complexes
MB Jones, AJ Gaunt - Chemical Reviews, 2013 - ACS Publications
The chemistry of the early to middle actinide elements (Th− Cm) is of critical importance to
the nuclear energy industry. A need for knowledge of the chemical behavior and speciation …
the nuclear energy industry. A need for knowledge of the chemical behavior and speciation …
Activation of small molecules by molecular uranium complexes
This chapter reviews the reaction chemistry of uranium complexes with small molecules of
industrial and biological importance. Specifically, carbon monoxide (CO), nitrogen monoxide …
industrial and biological importance. Specifically, carbon monoxide (CO), nitrogen monoxide …
[BOK][B] Progress in inorganic chemistry
KD Karlin, SJ Lippard - 2005 - Wiley Online Library
Lead has been used as a heavy atom derivative to solve the phase problem in the crystal
structures of a variety of protein including the calcium proteins calmodulin and …
structures of a variety of protein including the calcium proteins calmodulin and …
Uranium and manganese assembled in a wheel-shaped nanoscale single-molecule magnet with high spin-reversal barrier
Discrete molecular compounds that exhibit both magnetization hysteresis and slow
magnetic relaxation below a characteristic 'blocking'temperature are known as single …
magnetic relaxation below a characteristic 'blocking'temperature are known as single …
Tuning uranium–nitrogen multiple bond formation with ancillary siloxide ligands
The new homoleptic ate U (III) siloxide [K (18c6)][U (OSi (O t Bu) 3) 4] 2 was prepared in
69% yield by reduction of [U (OSi (O t Bu) 3) 4] 3 with KC8. The reaction of the neutral U (III) …
69% yield by reduction of [U (OSi (O t Bu) 3) 4] 3 with KC8. The reaction of the neutral U (III) …
Actinide-based single-molecule magnets
KR Meihaus, JR Long - Dalton Transactions, 2015 - pubs.rsc.org
Actinide single-molecule magnetism has experienced steady growth over the last five years
since the first discovery of slow magnetic relaxation in the mononuclear complex U …
since the first discovery of slow magnetic relaxation in the mononuclear complex U …
Strongly coupled binuclear uranium–oxo complexes from uranyl oxo rearrangement and reductive silylation
The most common motif in uranium chemistry is the d 0 f 0 uranyl ion [UO2] 2+ in which the
oxo groups are rigorously linear and inert. Alternative geometries, such as the cis-uranyl …
oxo groups are rigorously linear and inert. Alternative geometries, such as the cis-uranyl …