The renaissance of non‐aqueous uranium chemistry

ST Liddle - Angewandte Chemie International Edition, 2015 - Wiley Online Library
Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

Solution and solid-state structural chemistry of actinide hydrates and their hydrolysis and condensation products

KE Knope, L Soderholm - Chemical Reviews, 2013 - ACS Publications
Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and
Condensation Products | Chemical Reviews ACS ACS Publications C&EN CAS Find my …

Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [UVIO2]2+

BE Cowie, JM Purkis, J Austin, JB Love… - Chemical …, 2019 - ACS Publications
The uranyl ion,[UVIO2] 2+, possesses rigorously trans, strongly covalent, and chemically
robust U-oxo groups. However, through the use of anaerobic reaction techniques, both one …

Recent developments in synthesis and structural chemistry of nonaqueous actinide complexes

MB Jones, AJ Gaunt - Chemical Reviews, 2013 - ACS Publications
The chemistry of the early to middle actinide elements (Th− Cm) is of critical importance to
the nuclear energy industry. A need for knowledge of the chemical behavior and speciation …

Activation of small molecules by molecular uranium complexes

HS La Pierre, K Meyer - Progress in Inorganic Chemistry …, 2014 - Wiley Online Library
This chapter reviews the reaction chemistry of uranium complexes with small molecules of
industrial and biological importance. Specifically, carbon monoxide (CO), nitrogen monoxide …

[BOK][B] Progress in inorganic chemistry

KD Karlin, SJ Lippard - 2005 - Wiley Online Library
Lead has been used as a heavy atom derivative to solve the phase problem in the crystal
structures of a variety of protein including the calcium proteins calmodulin and …

Uranium and manganese assembled in a wheel-shaped nanoscale single-molecule magnet with high spin-reversal barrier

V Mougel, L Chatelain, J Pécaut, R Caciuffo… - Nature Chemistry, 2012 - nature.com
Discrete molecular compounds that exhibit both magnetization hysteresis and slow
magnetic relaxation below a characteristic 'blocking'temperature are known as single …

Tuning uranium–nitrogen multiple bond formation with ancillary siloxide ligands

C Camp, J Pecaut, M Mazzanti - Journal of the American Chemical …, 2013 - ACS Publications
The new homoleptic ate U (III) siloxide [K (18c6)][U (OSi (O t Bu) 3) 4] 2 was prepared in
69% yield by reduction of [U (OSi (O t Bu) 3) 4] 3 with KC8. The reaction of the neutral U (III) …

Actinide-based single-molecule magnets

KR Meihaus, JR Long - Dalton Transactions, 2015 - pubs.rsc.org
Actinide single-molecule magnetism has experienced steady growth over the last five years
since the first discovery of slow magnetic relaxation in the mononuclear complex U …

Strongly coupled binuclear uranium–oxo complexes from uranyl oxo rearrangement and reductive silylation

PL Arnold, GM Jones, SO Odoh, G Schreckenbach… - Nature Chemistry, 2012 - nature.com
The most common motif in uranium chemistry is the d 0 f 0 uranyl ion [UO2] 2+ in which the
oxo groups are rigorously linear and inert. Alternative geometries, such as the cis-uranyl …