Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis

D Leybo, UJ Etim, M Monai, SR Bare… - Chemical Society …, 2024 - pubs.rsc.org
Supported metal catalysts are essential to a plethora of processes in the chemical industry.
The overall performance of these catalysts depends strongly on the interaction of adsorbates …

Well-defined materials for heterogeneous catalysis: from nanoparticles to isolated single-atom sites

Z Li, S Ji, Y Liu, X Cao, S Tian, Y Chen, Z Niu… - Chemical …, 2019 - ACS Publications
The use of well-defined materials in heterogeneous catalysis will open up numerous new
opportunities for the development of advanced catalysts to address the global challenges in …

Dynamic interplay between metal nanoparticles and oxide support under redox conditions

H Frey, A Beck, X Huang, JA van Bokhoven… - Science, 2022 - science.org
The dynamic interactions between noble metal particles and reducible metal-oxide supports
can depend on redox reactions with ambient gases. Transmission electron microscopy …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Approaches for understanding and controlling interfacial effects in oxide-supported metal catalysts

I Ro, J Resasco, P Christopher - ACS Catalysis, 2018 - ACS Publications
Heterogeneous supported metal catalysts are critical for a wide range of chemical
conversion technologies. While the fundamental properties of extended metal surfaces are …

Size-dependent strong metal-support interaction in TiO2 supported Au nanocatalysts

X Du, Y Huang, X Pan, B Han, Y Su, Q Jiang… - Nature …, 2020 - nature.com
The strong metal-support interaction (SMSI) has long been studied in heterogonous
catalysis on account of its importance in stabilizing active metals and tuning catalytic …

Tuning/exploiting strong metal-support interaction (SMSI) in heterogeneous catalysis

CJ Pan, MC Tsai, WN Su, J Rick, NG Akalework… - Journal of the Taiwan …, 2017 - Elsevier
Interactions between metals and supports are of fundamental interest in heterogeneous
catalysis. The electronic, geometric and bifunctional effects originating from Strong Metal …

A New Type of Strong Metal–Support Interaction and the Production of H2 through the Transformation of Water on Pt/CeO2(111) and Pt/CeOx/TiO2(110) Catalysts

A Bruix, JA Rodriguez, PJ Ramírez… - Journal of the …, 2012 - ACS Publications
The electronic properties of Pt nanoparticles deposited on CeO2 (111) and CeO x/TiO2
(110) model catalysts have been examined using valence photoemission experiments and …

Nanocatalysis: size-and shape-dependent chemisorption and catalytic reactivity

BR Cuenya, F Behafarid - Surface Science Reports, 2015 - Elsevier
In recent years, the field of catalysis has experienced an astonishing transformation, driven
in part by more demanding environmental standards and critical societal and industrial …

The surface science of titanium dioxide

U Diebold - Surface science reports, 2003 - Elsevier
Titanium dioxide is the most investigated single-crystalline system in the surface science of
metal oxides, and the literature on rutile (110),(100),(001), and anatase surfaces is …