Biosynthesis of nitrogenase cofactors

S Burén, E Jiménez-Vicente… - Chemical …, 2020 - ACS Publications
Nitrogenase harbors three distinct metal prosthetic groups that are required for its activity.
The simplest one is a [4Fe-4S] cluster located at the Fe protein nitrogenase component. The …

Nitrate and periplasmic nitrate reductases

C Sparacino-Watkins, JF Stolz, P Basu - Chemical Society Reviews, 2014 - pubs.rsc.org
The nitrate anion is a simple, abundant and relatively stable species, yet plays a significant
role in global cycling of nitrogen, global climate change, and human health. Although it has …

Diversity in ABC transporters: type I, II and III importers

AJ Rice, A Park, HW Pinkett - Critical reviews in biochemistry and …, 2014 - Taylor & Francis
ATP-binding cassette transporters are multi-subunit membrane pumps that transport
substrates across membranes. While significant in the transport process, transporter …

Structural basis of trans-inhibition in a molybdate/tungstate ABC transporter

S Gerber, M Comellas-Bigler, BA Goetz, KP Locher - Science, 2008 - science.org
Transport across cellular membranes is an essential process that is catalyzed by diverse
membrane transport proteins. The turnover rates of certain transporters are inhibited by their …

Molybdate transport and regulation in bacteria

AM Grunden, KT Shanmugam - Archives of microbiology, 1997 - Springer
Molybdate is transported in bacteria by a high-affinity transport system composed of a
periplasmic binding protein, an integral membrane protein, and an energizer protein. These …

Overview of physiological, biochemical, and regulatory aspects of nitrogen fixation in Azotobacter vinelandii

JS Martin del Campo, J Rigsbee… - Critical Reviews in …, 2022 - Taylor & Francis
Understanding how Nature accomplishes the reduction of inert nitrogen gas to form
metabolically tractable ammonia at ambient temperature and pressure has challenged …

Molybdate transport

WT Self, AM Grunden, A Hasona… - Research in …, 2001 - Elsevier
In both bacteria and archaea, molybdate is transported by an ABC-type transporter
comprising three proteins, ModA (periplasmic binding protein), ModB (membrane protein) …

Essential metals for nitrogen fixation in a free‐living N2‐fixing bacterium: chelation, homeostasis and high use efficiency

JP Bellenger, T Wichard, Y Xu… - Environmental …, 2011 - Wiley Online Library
Biological nitrogen fixation, the main source of new nitrogen to the Earth's ecosystems, is
catalysed by the enzyme nitrogenase. There are three nitrogenase isoenzymes: the Mo …

Specificity of NifEN and VnfEN for the assembly of nitrogenase active site cofactors in Azotobacter vinelandii

A Pérez-González, E Jimenez-Vicente, J Gies-Elterlein… - MBio, 2021 - Am Soc Microbiol
The nitrogen-fixing microbe Azotobacter vinelandii has the ability to produce three
genetically distinct, but mechanistically similar, components that catalyze nitrogen fixation …

ModE-Dependent Molybdate Regulation of the Molybdenum Cofactor Operon moa in Escherichia coli

LA Anderson, E McNairn, T Leubke, RN Pau… - Journal of …, 2000 - Am Soc Microbiol
The expression of the moa locus, which encodes enzymes required for molybdopterin
biosynthesis, is enhanced under anaerobiosis but repressed when the bacterium is able to …