Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …

Polyoxometalates are clusters of metal-oxide units, comprising a large diversity of nanoscale
structures, and have many common building blocks; in fact polyoxometalate clusters are …

Only rarely have polyoxometalates been found to form core–shell nanoclusters. Here, we
succeeded in isolating a series of rare giant and all‐inorganic core–shell cobalt …

During the past decade, research into transition-metal-substituted polyoxometalate self-
assembly has been greatly developed. This review summarizes the conventional solution …

A series of all-inorganic, abundant-metal-based, high-nuclearity cobalt–phosphate (Co–Pi)
molecular catalysts [{Co4 (OH) 3 (PO4)} 4 (SiW9O34) 4] 32–(1),[{Co4 (OH) 3 (PO4)} 4 …

Inorganic oxide materials are used in semiconductor electronics, ion exchange, catalysis,
coatings, gas sensors and as separation materials. Although their synthesis is well …

This critical review surveys the 3d substituted magnetic polyoxotungstate (POT) molecular
compounds reported these last ten years, illustrating the huge variety of topologies that …

Synergistic directing roles of six lacunary fragments resulted in an unprecedented Zr24-
cluster substituted poly (polyoxotungstate) Na10K22 [Zr24O22 (OH) 10 (H2O) 2 (W2O10H) 2 …

As is well known, carbon dioxide (CO 2) reduction reaction (CO 2 RR) by photocatalytic
technology is a means with great promise to alleviate the crises on the global energy and …

Abstract The {Mn 4 O 5 Ca} cluster of photosystem II is a well-known cubane-like transition-
metal (TM) cluster that plays important roles in solar energy conversion. The artificial …