Pillar-layered MOFs: functionality, interpenetration, flexibility and applications
Pillar-layered metal–organic frameworks (MOFs) are among the most interesting research
areas in crystalline materials. Due to the great number of reports related to pillar-layered …
areas in crystalline materials. Due to the great number of reports related to pillar-layered …
Multi-dimensional metal-organic frameworks based on mixed linkers: Interplay between structural flexibility and functionality
Metal-organic frameworks (MOFs) are regarded widely because of their intriguing structural
dynamism, which sets them apart from other porous materials. Such structural flexibility or …
dynamism, which sets them apart from other porous materials. Such structural flexibility or …
Functionalization of metal–organic frameworks for photoactive materials
Metal–organic frameworks (MOFs) are intriguing platforms with multiple functionalities.
Additional functionalization of MOFs generates novel materials for various applications …
Additional functionalization of MOFs generates novel materials for various applications …
A multistimulus responsive porous coordination polymer: temperature-mediated control of solid-state [2+ 2] cycloaddition
Either of two different isomeric products can be selectively obtained by photochemical [2+ 2]
cycloaddition of 1, 4-bis [2-(4-pyridyl) ethenyl]-benzene within a porous coordination …
cycloaddition of 1, 4-bis [2-(4-pyridyl) ethenyl]-benzene within a porous coordination …
Spin-crossover modulation via single-crystal to single-crystal photochemical [2+ 2] reaction in Hofmann-type frameworks
LF Wang, WM Zhuang, GZ Huang, YC Chen… - Chemical …, 2019 - pubs.rsc.org
This study reports the first modulation of spin-crossover (SCO) behavior via a photochemical
[2+ 2] cycloaddition reaction. Here we construct two no-solvent Fe (II)–Ag (I) bimetallic …
[2+ 2] cycloaddition reaction. Here we construct two no-solvent Fe (II)–Ag (I) bimetallic …
Cadmium (II) coordination polymers of 4-pyr-poly-2-ene and carboxylates: construction, structure, and photochemical double [2+ 2] cycloaddition and luminescent …
WJ Gong, ZG Ren, HX Li, JG Zhang… - Crystal Growth & …, 2017 - ACS Publications
Solvothermal reactions of Cd (NO3) 2· 4H2O with 4-pyr-poly-2-ene (ppene) in the presence
of benzene-1, 2-dicarboxylic acid (1, 2-H2BDC), benzene-1, 3-dicarboxylic acid (1, 3 …
of benzene-1, 2-dicarboxylic acid (1, 2-H2BDC), benzene-1, 3-dicarboxylic acid (1, 3 …
Dynamic topochemical reaction tuned by guest molecules in the nanospace of a metal–organic framework
Reaction in well-designed solids allows yielding products with high selectivity and unique
compounds that cannot be obtained in solution. However, the precise tuning of the …
compounds that cannot be obtained in solution. However, the precise tuning of the …
Solvent‐Mediated Synthesis of Cyclobutane Isomers in a Photoactive Cadmium (II) Porous Coordination Polymer
Abstract Photochemical [2+ 2] cycloaddition of 1, 4‐bis [2‐(4‐pyridyl) ethenyl] benzene,
carried out in a CdII porous coordination polymer (PCP), produces different isomeric …
carried out in a CdII porous coordination polymer (PCP), produces different isomeric …
CO 2-induced single-crystal to single-crystal transformations of an interpenetrated flexible MOF explained by in situ crystallographic analysis and molecular modeling
A molecular-level investigation is reported on breathing behaviour of a metal–organic
framework (1) in response to CO2 gas pressure. High-pressure gas adsorption shows a …
framework (1) in response to CO2 gas pressure. High-pressure gas adsorption shows a …
Turning flexibility into rigidity: stepwise locking of interpenetrating networks in a MOF crystal through click reaction
Post-synthetic modifications of metal–organic frameworks (MOFs) enable synthesis of
materials with enhanced performance characteristics or those inaccessible by direct …
materials with enhanced performance characteristics or those inaccessible by direct …