Role of Solvation Dynamics and Local Ordering of Water in Inducing Conformational Transitions in Poly(N-isopropylacrylamide) Oligomers through the LCST
Conformational transitions in thermo-sensitive polymers are critical in determining their
functional properties. The atomistic origin of polymer collapse at the lower critical solution …
functional properties. The atomistic origin of polymer collapse at the lower critical solution …
Flory-type theories of polymer chains under different external stimuli
YA Budkov, MG Kiselev - Journal of Physics: Condensed Matter, 2017 - iopscience.iop.org
In this Review, we present a critical analysis of various applications of the Flory-type theories
to a theoretical description of the conformational behavior of single polymer chains in dilute …
to a theoretical description of the conformational behavior of single polymer chains in dilute …
Understanding anti‐polyelectrolyte behavior of a well‐defined polyzwitterion at the single‐chain level
F Wang, J Yang, J Zhao - Polymer international, 2015 - Wiley Online Library
A study was made of the anti‐polyelectrolyte effect of a model polyzwitterion at the single‐
chain level and from the point of view of comparison with inorganic salts and organic inner …
chain level and from the point of view of comparison with inorganic salts and organic inner …
Cononsolvency effect: when the hydrogen bonding between a polymer and a cosolvent matters
Despite the fact that the observation of cononsolvency was reported as early as four
decades ago, its phase-transition mechanism is still under debate. In this work, we provided …
decades ago, its phase-transition mechanism is still under debate. In this work, we provided …
Preferential adsorption and co-nonsolvency of thermoresponsive polymers in mixed solvents of water/methanol
F Tanaka, T Koga, H Kojima, N Xue, FM Winnik - Macromolecules, 2011 - ACS Publications
If two good solvents become poor for a polymer when mixed, the solvent pair is called a co-
nonsolvent pair for the polymer. The sharp depression of the LCST by the co-nonsolvency in …
nonsolvent pair for the polymer. The sharp depression of the LCST by the co-nonsolvency in …
Dynamics of gold nanoparticles in a polymer melt
Gold nanoparticles are used as a luminescent contrast agent to study size-dependent
dynamics in polymer matrix. The experiments measured the diffusion coefficient of particles …
dynamics in polymer matrix. The experiments measured the diffusion coefficient of particles …
Conformational Transition of Poly(N-isopropylacrylamide) Single Chains in Its Cononsolvency Process: A Study by Fluorescence Correlation Spectroscopy and …
Fluorescence correlation spectroscopy (FCS) has been adopted to investigate the
conformational transition of poly (N-isopropylacrylamide)(PNIPAM) single chains with …
conformational transition of poly (N-isopropylacrylamide)(PNIPAM) single chains with …
Conformation Transition of a Homopolymer Chain in Binary Mixed Solvents
On the basis of a minimal lattice model, we apply the Wang–Landau Monte Carlo (MC)
algorithm and a Flory-type mean-field theory to investigate the conformation of a …
algorithm and a Flory-type mean-field theory to investigate the conformation of a …
Unusual transformation of polymer coils in a mixed solvent close to the critical point
We have discovered unusual behavior of polymer coils in a binary solvent (nitroethane+
isooctane) near the critical temperature of demixing. The exceptionally close refractive …
isooctane) near the critical temperature of demixing. The exceptionally close refractive …
A Comparison between the lower critical solution temperature behavior of polymers and biomacromolecules
All-atom molecular dynamics (MD) simulations are employed to compare the lower critical
solution temperature (LCST) behaviors of poly (N-isopropylacrylamide)(PNIPAM) and …
solution temperature (LCST) behaviors of poly (N-isopropylacrylamide)(PNIPAM) and …