Colloidal hard spheres: Triumphs, challenges, and mysteries

CP Royall, P Charbonneau, M Dijkstra, J Russo… - Reviews of Modern …, 2024 - APS
The simplicity of hard spheres as a model system is deceptive. Although the particles
interact solely through volume exclusion, that nevertheless suffices for a wealth of static and …

Direct imaging of the kinetic crystallization pathway: simulation and liquid-phase transmission electron microscopy observations

Z Xu, Z Ou - Materials, 2023 - mdpi.com
The crystallization of materials from a suspension determines the structure and function of
the final product, and numerous pieces of evidence have pointed out that the classical …

Fcc vs. hcp competition in colloidal hard-sphere nucleation: on their relative stability, interfacial free energy and nucleation rate

I Sanchez-Burgos, E Sanz, C Vega… - Physical Chemistry …, 2021 - pubs.rsc.org
Hard-sphere crystallization has been widely investigated over the last six decades by means
of colloidal suspensions and numerical methods. However, some aspects of its nucleation …

An Artificial Neural Network Reveals the Nucleation Mechanism of a Binary Colloidal AB13 Crystal

GM Coli, M Dijkstra - ACS nano, 2021 - ACS Publications
Colloidal suspensions of two species have the ability to form binary crystals under certain
conditions. The hunt for these functional materials and the countless investigations on their …

Hard sphere crystal nucleation rates: Reconciliation of simulation and experiment

W Wöhler, T Schilling - Physical Review Letters, 2022 - APS
Over the past two decades, a large number of studies addressed the topic of crystal
nucleation in suspensions of hard spheres. The shared result of all these efforts is that, at …

Hydrodynamic interactions hinder transport of flow-driven colloidal particles

D Lips, E Cereceda-López, A Ortiz-Ambriz, P Tierno… - Soft Matter, 2022 - pubs.rsc.org
The flow-driven transport of interacting micron-sized particles occurs in many soft matter
systems spanning from the translocation of proteins to moving emulsions in microfluidic …

Spontaneous crystallization in systems of binary hard sphere colloids

PK Bommineni, M Klement, M Engel - Physical Review Letters, 2020 - APS
Computer simulations of the fluid-to-solid phase transition in the hard sphere system were
instrumental for our understanding of crystallization processes. But while colloid …

Are neural network potentials trained on liquid states transferable to crystal nucleation? A test on ice nucleation in the mw water model

F Guidarelli Mattioli, F Sciortino… - The Journal of Physical …, 2023 - ACS Publications
Neural network potentials (NNPs) are increasingly being used to study processes that
happen on long time scales. A typical example is crystal nucleation, which rate is controlled …

The effect of hydrodynamics on the crystal nucleation of nearly hard spheres

G Fiorucci, GM Coli, JT Padding… - The Journal of Chemical …, 2020 - pubs.aip.org
We investigate the effect of hydrodynamic interactions (HIs) on the crystal nucleation of hard-
sphere colloids for varying supersaturations. We use molecular dynamics and stochastic …

The impact of colloid-solvent dynamic coupling on the coarsening rate of colloidal phase separation

M Tateno, J Yuan, H Tanaka - Journal of Colloid and Interface Science, 2025 - Elsevier
Phase separation, a fundamental phenomenon in both natural and industrial settings,
involves the coarsening of domains over time t to reduce interfacial energy. While well …