Nanoconfinement-mediated water treatment: from fundamental to application

J Qian, X Gao, B Pan - Environmental Science & Technology, 2020 - ACS Publications
Safe and clean water is of pivotal importance to all living species and the ecosystem on
earth. However, the accelerating economy and industrialization of mankind generate water …

Confinement-controlled aqueous chemistry within nanometric slit pores: Focus review

D Munoz-Santiburcio, D Marx - Chemical Reviews, 2021 - ACS Publications
In this Focus Review, we put the spotlight on very recent insights into the fascinating world of
wet chemistry in the realm offered by nanoconfinement of water in mechanically rather rigid …

Cation-and pH-dependent hydrogen evolution and oxidation reaction kinetics

B Huang, RR Rao, S You, K Hpone Myint, Y Song… - Jacs Au, 2021 - ACS Publications
The production of molecular hydrogen by catalyzing water splitting is central to achieving the
decarbonization of sustainable fuels and chemical transformations. In this work, a series of …

Confined water's dielectric constant reduction is due to the surrounding low dielectric media and not to interfacial molecular ordering

JF Olivieri, JT Hynes, D Laage - The Journal of Physical Chemistry …, 2021 - ACS Publications
Liquid water confined within nanometer-sized channels exhibits a surprisingly low dielectric
constant along the direction orthogonal to the channel walls. This is typically assumed to …

Universal reduction in dielectric response of confined fluids

MH Motevaselian, NR Aluru - ACS nano, 2020 - ACS Publications
Dielectric permittivity is central to many biological and physiochemical systems, as it affects
the long-range electrostatic interactions. Similar to many fluid properties, confinement …

Molecular dynamics simulations of the colloidal interaction between smectite clay nanoparticles in liquid water

X Shen, IC Bourg - Journal of Colloid and Interface Science, 2021 - Elsevier
Colloidal interactions between clay nanoparticles have been studied extensively because of
their strong influence on the hydrology and mechanics of many soils and sedimentary …

Ion and water adsorption to graphene and graphene oxide surfaces

AJ Carr, SE Lee, A Uysal - Nanoscale, 2023 - pubs.rsc.org
Graphene and graphene oxide (GO) are two particularly promising nanomaterials for a
range of applications including energy storage, catalysis, and separations. Understanding …

Cation-dependent interfacial structures and kinetics for outer-sphere electron-transfer reactions

B Huang, KH Myint, Y Wang, Y Zhang… - The Journal of …, 2021 - ACS Publications
The kinetics of aqueous outer-sphere electron-transfer (ET) reactions are determined in
large part by noncovalent electrostatic interactions that originate from the surrounding …

Suppressed terahertz dynamics of water confined in nanometer gaps

H Yang, G Ji, M Choi, S Park, H An, HT Lee… - Science …, 2024 - science.org
Nanoconfined waters exhibit low static permittivity mainly due to interfacial effects that span
about one nanometer. The characteristic length scale may be much longer in the terahertz …

Abnormal Properties of Low‐Dimensional Confined Water

D Wang, Y Tian, L Jiang - Small, 2021 - Wiley Online Library
Water molecules confined to low‐dimensional spaces exhibit unusual properties compared
to bulk water. For example, the alternating hydrophilic and hydrophobic nanodomains on flat …