Colloidal hard spheres: Triumphs, challenges, and mysteries

CP Royall, P Charbonneau, M Dijkstra, J Russo… - Reviews of Modern …, 2024 - APS
The simplicity of hard spheres as a model system is deceptive. Although the particles
interact solely through volume exclusion, that nevertheless suffices for a wealth of static and …

Spearheading a new era in complex colloid synthesis with TPM and other silanes

M Kamp, S Sacanna, RPA Dullens - Nature Reviews Chemistry, 2024 - nature.com
Colloid science has recently grown substantially owing to the innovative use of silane
coupling agents (SCAs), especially 3-trimethoxysilylpropyl methacrylate (TPM). SCAs were …

Sha** colloidal bananas to reveal biaxial, splay-bend nematic, and smectic phases

C Fernández-Rico, M Chiappini, T Yanagishima… - Science, 2020 - science.org
Understanding the impact of curvature on the self-assembly of elongated microscopic
building blocks, such as molecules and proteins, is key to engineering functional materials …

Enabling three-dimensional real-space analysis of ionic colloidal crystallization

S Zang, AW Hauser, S Paul, GM Hocky, S Sacanna - Nature Materials, 2024 - nature.com
Structures of molecular crystals are identified using scattering techniques because we
cannot see inside them. Micrometre-sized colloidal particles enable the real-time …

Synthetic strategies for nonporous organosilica nanoparticles from organosilanes

H Zou, Y Ren - Nanoscale, 2023 - pubs.rsc.org
Organosilica nanoparticles refer to silica nanoparticles containing carbon along with organic
or functional groups and can be divided into mesoporous organosilica nanoparticles and …

Microgel dynamics within the 3D porous structure of transparent PEG hydrogels

G Bassu, M Laurati, E Fratini - Colloids and Surfaces B: Biointerfaces, 2023 - Elsevier
We report an investigation on the effects of the confinement imposed by application-relevant
poly (ethylene glycol)(PEG) hydrogel matrices with controlled porosity on the dynamics of …

Particle-level visualization of hydrodynamic and frictional couplings in dense suspensions of spherical colloids

T Yanagishima, Y Liu, H Tanaka, RPA Dullens - Physical Review X, 2021 - APS
The rotational Brownian motion of colloidal spheres in dense suspensions reflects local
hydrodynamics and contact forces, which are both key to nonlinear rheological phenomena …

Distinct Contributions of Particle Adsorption and Interfacial Compression to the Surface Pressure of a Fluid Interface

Y Fu, J Frechette - Langmuir, 2024 - ACS Publications
Particle-laden interfaces stabilize emulsions and foams and can serve as a platform for
multiscale materials. Favorable wetting of a particle to a fluid interface reduces the apparent …

Inorganic–Organic Hybrid Copolymeric Colloids as Multicolor Emission, Fuel‐Free, UV‐and Visible‐Light‐Actuated Micropumps

M Basharat, ZH Shah, M Ikram, SE Ghellab… - Small, 2022 - Wiley Online Library
Light‐actuated micromachines are of enormous interest due to their ability to harvest light for
triggering catalytic reactions to acquire free energy for mechanical work. This work presents …

Refractive-index and density-matched emulsions with programmable DNA interactions

W Chen, L Sixdenier, A McMullen, DG Grier, J Brujic - Soft Matter, 2024 - pubs.rsc.org
Emulsion droplets on the colloidal length scale are a model system of frictionless compliant
spheres. Direct imaging studies of the microscopic structure and dynamics of emulsions offer …