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Critical review on the degradation mechanisms and recent progress of Ni-rich layered oxide cathodes for lithium-ion batteries
Ni-rich layered transition metal oxides possess remarkably high capacity and thus are very
competitive cathode materials in high-energy lithium-ion batteries (LIBs) for electric vehicles …
competitive cathode materials in high-energy lithium-ion batteries (LIBs) for electric vehicles …
Cracking vs. surface reactivity in high-nickel cathodes for lithium-ion batteries
High-nickel layered oxide cathodes LiNi x Mn y Co z O 2 (NMC) experience microcracks
during cycling. This can expose fresh cathode surfaces for parasitic reactions and isolate …
during cycling. This can expose fresh cathode surfaces for parasitic reactions and isolate …
Advances and perspectives in understanding the structure-redox relationship of layered Li-Co-Ni-Mn oxide cathode materials
A comprehensive understanding of the relationship between the structure
(electron/bulk/surface structures) and redox chemistry in the cathodes was discussed in this …
(electron/bulk/surface structures) and redox chemistry in the cathodes was discussed in this …
[HTML][HTML] Deciphering and modulating energetics of solvation structure enables aggressive high-voltage chemistry of Li metal batteries
The stability of localized high-concentrated electrolytes (LHCEs) on the Li metal anode has
been well established, but the understanding of its oxidation chemistry for high-voltage …
been well established, but the understanding of its oxidation chemistry for high-voltage …
Factors Influencing Gas Evolution from High‐Nickel Layered Oxide Cathodes in Lithium‐Based Batteries
Gas evolution from high‐nickel layered oxide cathodes (> 90% Ni) remains a major issue for
their practical application. Gaseous species, such as CO2, O2, and CO, that are evolved at …
their practical application. Gaseous species, such as CO2, O2, and CO, that are evolved at …
Localized High‐Concentration Electrolytes with Low‐Cost Diluents Compatible with Both Cobalt‐Free LiNiO2 Cathode and Lithium‐Metal Anode
High‐nickel layered oxide cathodes and lithium‐metal anode are promising candidates for
next‐generation battery systems due to their high energy density. Nevertheless, the …
next‐generation battery systems due to their high energy density. Nevertheless, the …
Impact of dopants on suppressing gas evolution from high-nickel layered oxide cathodes
Gas release from high-Ni layered oxide cathodes (LiNi x Mn1-xyz Co y Al z O2; x> 0.8) can
jeopardize the overall performance and safety characteristics of the cell. A comprehensive …
jeopardize the overall performance and safety characteristics of the cell. A comprehensive …
Crossover effects in lithium‐metal batteries with a localized high concentration electrolyte and high‐nickel cathodes
J Langdon, A Manthiram - Advanced Materials, 2022 - Wiley Online Library
While crossover effects, such as transition‐metal dissolution, are well‐understood in lithium‐
ion batteries, there is a limited understanding of the effect of crossed‐over chemical species …
ion batteries, there is a limited understanding of the effect of crossed‐over chemical species …
Protection of Cobalt-Free LiNiO2 from Degradation with Localized Saturated Electrolytes in Lithium-Metal Batteries
High-nickel layered oxide cathode materials are the most promising candidates for
develo** lithium-metal batteries (LMBs) because of their high energy density and low cost …
develo** lithium-metal batteries (LMBs) because of their high energy density and low cost …
In situ interweaved binder framework mitigating the structural and interphasial degradations of High‐nickel cathodes in lithium‐ion batteries
The practical viability of high‐nickel layered oxide cathodes is compromised by the
interphasial and structural degradations. Herein, we demonstrate that by applying an in situ …
interphasial and structural degradations. Herein, we demonstrate that by applying an in situ …